1. Institute of Structural Engineering, Zhejiang University, Hangzhou 310058, China 2. School of Civil Engineering and Architecture, Ningbo Institute of Technology, Zhejiang University, Ningbo 315100, China 3. Hangzhou Bay Cross-sea Bridge Development Co. Ltd, Ningbo 315317, China
The bi-directional electro-migration (BIEM) method was used to repair the cracked concrete in the marine environment, in order to eliminate the chloride enriched in the vicinity of the crack and to prevent corrosion of the steel bars. The effect of BIEM under different crack widths was studied by measuring the concentration of rust inhibitor, mass fraction of chloride ion and the polarization curve of reinforcement. The chloride migration law was verified by the chloride migration characteristic test. Results that the corrosion potential of the steel can be restored to a high level after BIEM of the cracked concrete. When the crack width is small, the migration law of chloride ion in concrete cover is similar to that of the uncracked concrete. When the cracked width in concrete is greater than 0.3 mm, the chloride ion discharge efficiency at the crack increases with the increase of the crack width, while the discharge efficiency of chloride ion farther from the crack decreases.
Fei-bin YUAN,Wei-liang JIN,Jiang-hong MAO,Jin-quan WANG,Wei-jie FAN,Jin XIA. Effect of chloride removal and corrosion prevention for cracked concrete based on bi-directional electro-migration rehabilitation. Journal of ZheJiang University (Engineering Science), 2019, 53(12): 2317-2324.
Fig.1Schematic diagram of bi-directional electro-migration(BIEM)in cracked concrete
Fig.2Schematic diagram of potential distribution in cracked concrete when electrified
编号
ρ /(kg·m?3)
水
水泥
砂子
石子
氯化钠
C30
206.7
406.7
633.3
1050
20.3
Tab.1Mix proportion of C30 concrete specimen
Fig.3Schematic diagram of BIEM specimen and chloride ion migration characteristic test specimen
Fig.4Powder picking position along direction of specimen length and concrete cover
Fig.5Polarization curve of steel bars in specimen groups with different crack widths before and after BIEM
试件组
Ecorr /mV
$ E'_{\rm{corr}}$/mV
单值
均值
单值
均值
A-0
?480
?463
?180
?172
?456
?191
?455
?145
A-0.1
?431
?430
?162
?166
?391
?157
?468
?180
A-0.3
?430
?437
?157
?161
?448
?179
?432
?146
A-0.5
?484
?457
?182
?166
?436
?155
?452
?162
A-0.7
?476
?491
?142
?160
?504
?156
?494
?183
A-1.0
?501
?470
?158
?149
?414
?143
?494
?147
Tab.2Corrosion potential before and after bi-directional electro-migration(BIEM)
Fig.6Distribution of chloride concentration in concrete cover after BIEM
Fig.7Schematic diagram for color boundary of each specimen
Fig.8Distribution of color boundary of specimen with different crack widths
Fig.9Location distribution of each specimen with fixed mass fraction value of chloride ion(0.03%)
Fig.10Comparison of chloride ion mass fractions at different locations on surface layer of steel bar
Fig.11Comparison of molar concentration of TETA in layer near steel bar
w/mm
x0 /mm
R
w/mm
x0 /mm
R
0
0
28.36
0.1
0
26.54
20
27.16
20
26.24
60
28.80
60
25.24
0.3
0
33.05
0.5
0
31.97
20
27.99
20
27.24
60
28.60
60
28.93
0.7
0
36.49
1.0
0
45.13
20
20.72
20
15.13
60
17.70
60
10.8
Tab.3Molar concentration ratio of TETA and chloride ion in layer near steel bar
[1]
陈肇元, 崔京浩, 朱金铨, 等 钢筋混凝土裂缝机理与控制措施[J]. 工程力学, 2006, 23 (a01): 86- 107 CHEN Zhao-yuan, CUI Jing-hao, ZHU Jin-quan, et al Analysis and control of cracking in reinforced concrete[J]. Engineering Mechanics, 2006, 23 (a01): 86- 107
[2]
DJERBI A, BONNET S, KHELIDJ A, et al Influence of traversing crack on chloride diffusion into concrete[J]. Cement and Concrete Research, 2008, 38 (6): 877- 883
doi: 10.1016/j.cemconres.2007.10.007
[3]
SAHMARAN M Effect of flexure induced transverse crack and self-healing on chloride diffusivity of reinforced mortar[J]. Journal of Materials Science, 2007, 42 (22): 9131- 9136
doi: 10.1007/s10853-007-1932-z
[4]
金祖权, 侯保荣, 赵铁军, 等 收缩裂缝对混凝土氯离子渗透及碳化的影响[J]. 土木建筑与环境工程, 2011, 33 (1): 7- 11 JIN Zu-quan, HOU Bao-rong, ZHAO Tie-jun, et al Influence of shrinkage cracks on chloride penetration and crabonation of concrete[J]. Journal of Civil Architectural and Environmental Engineering, 2011, 33 (1): 7- 11
doi: 10.11835/j.issn.1674-4764.2011.01.003
[5]
延永东, 金伟良, 王海龙 饱和状态下开裂混凝土内的氯离子输运[J]. 浙江大学学报: 工学版, 2011, 45 (12): 2127- 2133 YAN Yong-dong, JIN Wei-liang, WANG Hai-long Chloride ingression in cracked concrete under saturated state[J]. Journal of Zhejiang University: Engineering Science, 2011, 45 (12): 2127- 2133
[6]
POLDER R B Electrochemical chloride removal from concrete prisms containing chloride penetrated from sea water[J]. Construction and Building Materials, 1996, 10 (1): 83- 88
doi: 10.1016/0950-0618(95)00062-3
[7]
ORELLAN J C, ESCADEILLAS G, ARLIGUIE G Electrochemical chloride extraction: efficiency and side effects[J]. Cement and Concrete Research, 2004, 34 (2): 227- 234
doi: 10.1016/j.cemconres.2003.07.001
[8]
SAWADA S, PAGE C L, PAGE M M Electrochemical injection of organic corrosion inhibitors into concrete[J]. Corrosion Science, 2005, 47 (8): 2063- 2078
doi: 10.1016/j.corsci.2004.10.001
[9]
TANG J, HAN S, HUANG C, et al Investigation on inhibitor electromigration anticorrosion technology for reinforced concrete structure[J]. Advanced Materials Research, 2009, 79-82: 1025- 1028
doi: 10.4028/www.scientific.net/AMR.79-82.1025
[10]
XU C, JIN W L, HUANG N, et al Bidirectional electromigration of a corrosion inhibitor in chloride contaminated concrete[J]. Magazine of Concrete Research, 2015, 68 (9): 1- 12
[11]
许晨, 金伟良, 章思颖 氯盐侵蚀混凝土结构延寿技术初探Ⅱ: 混凝土中6种胺类有机物电迁移与阻锈性能[J]. 建筑材料学报, 2014, 17 (4): 572- 578 XU Chen, JIN Wei-liang, ZHANG Si-ying Preliminary study on service life extension of concrete structures under chloride environment: effectiveness of six amine-based inhibitors for steel in chloride-contaminated simulated concrete pore solutions[J]. Journal of Building Materials, 2014, 17 (4): 572- 578
doi: 10.3969/j.issn.1007-9629.2014.04.003
[12]
金伟良, 黄楠, 许晨, 等 双向电渗对钢筋混凝土修复效果的试验研究: 保护层阻锈剂、氯离子和总碱度的变化规律[J]. 浙江大学学报: 工学版, 2014, 48 (9): 1586- 1594 JIN Wei-liang, HUANG Nan, XU Chen, et al Experimental research on effect of bidirectional electromigration rehabilitation on reinforced concrete: concentration changes of inhibitor, chloride ions and total alkalinity[J]. Journal of Zhejiang University: Engineering Science, 2014, 48 (9): 1586- 1594
[13]
毛江鸿, 金伟良, 李志远, 等 氯盐侵蚀钢筋混凝土桥梁耐久性提升及寿命预测[J]. 中国公路学报, 2016, 29 (1): 61- 66 MAO Jiang-hong, JIN Wei-liang, LI Zhi-yuan, et al Durability improvement and service life prediction of reinforced concrete bridge under chloride attack[J]. China Journal of Highway and Transport, 2016, 29 (1): 61- 66
doi: 10.3969/j.issn.1001-7372.2016.01.008
[14]
RYU J S, OTSUKI N Crack closure of reinforced concrete by electrodeposition technique[J]. Cement and Concrete Research, 2002, 32 (1): 159- 164
doi: 10.1016/S0008-8846(01)00650-0
[15]
NISHIDA T , OTSUKI N , SAITO A . Development of improved electrodeposition method for repair of reinforced concrete structures [C] // 4th International Conference on the Durability of Concrete Structures. West Lafayette: ICDCS, 2014: 393−402.
[16]
姚武, 郑晓芳 电沉积法修复钢筋混凝土裂缝的试验研究[J]. 同济大学学报: 自然科学版, 2006, 34 (11): 1441- 1444 YAO Wu, ZHENG Xiao-fang Experimental study on crack repair of reinforced concrete by electrodeposition technique[J]. Journal of Tongji University: Natural Science, 2006, 34 (11): 1441- 1444
[17]
宋显辉, 张华, 李卓球 碳纤维增强混凝土裂纹钝化的有限元模拟与实验研究[J]. 华中科技大学学报: 城市科学版, 2003, 20 (3): 26- 29 SONG Xian-hui, ZHANG Hua, LI Zhuo-qiu Study of crack blunting in carbon fibre reinforced concrete and finite element simulation[J]. Journal of Huazhong University of Science and Technology: Urban Science Edition, 2003, 20 (3): 26- 29
[18]
金伟良, 郭柱, 许晨 电化学修复后钢筋极化状态分析[J]. 中国腐蚀与防护学报, 2013, 33 (1): 75- 80 JIN Wei-liang, GUO Zhu, XU Chen Polarization analysis of reinforced after electrochemical repair[J]. Journal of Chinese Society for Corrosion and Protection, 2013, 33 (1): 75- 80
[19]
ASsTM C876-91, Standard test method for half-cell potentials of uncoated reinforcing steel in concrete [S]. New York: ANSI, 1999.