Please wait a minute...
J4  2011, Vol. 45 Issue (10): 1877-1883    DOI: 10.3785/j.issn.1008-973X.2011.10.029
    
Characteristics and sintering technology of haydite
made of sewage sludge
WENG Huan-xin, ZHANG Jin-jun, CAO Yan-sheng, MA Xue-wen
Institute of Environment & Biogeochemistry, Zhejiang University, Hangzhou 310027, China
Download:   PDF(0KB) HTML
Export: BibTeX | EndNote (RIS)      

Abstract  

The characteristics of sludge haydite and sintering technology were analyzed based on systematic analysis on the physicochemical properties of sludge in order to provide a new way to sinter haydite by sewage sludge. A sintering technology integrated with sludge drying was established combined with the characteristics of sludge drying at lowtemperature. Results showed that the mass fraction of Al2O3 and Na2O+K2O in sludge was suitable to sinter haydite, and the mass fraction of SiO2 was near to 48% which is the lower limit of sintering haydite, therefore the sludge met the basic conditions to sinter haydite. The compressive strength of haydite increased with the increase of apparent density. Sintering temperature had great impact on the compressive strength and apparent density of haydite. Sintered haydite had maximum compressive strength (71.7 MPa) and apparent density (2.45 g/cm3)at 1 075 ℃. The water absorbing capacity of haydite decreased with the increase of sintering temperature.



Published: 01 October 2011
CLC:  X 705  
Cite this article:

WENG Huan-xin, ZHANG Jin-jun, CAO Yan-sheng, MA Xue-wen. Characteristics and sintering technology of haydite
made of sewage sludge. J4, 2011, 45(10): 1877-1883.

URL:

https://www.zjujournals.com/eng/10.3785/j.issn.1008-973X.2011.10.029     OR     https://www.zjujournals.com/eng/Y2011/V45/I10/1877


污泥陶粒的性能特征与烧制工艺

为了探索污泥烧制陶粒的新方法,在系统分析污泥理化性质的基础上,研究污泥陶粒的制备工艺及性能.结合污泥低温干化的技术特点,建立污泥干化与陶粒烧制一体化的工艺流程.研究结果表明,污泥的Al2O3和Na2O+K2O质量分数在可用于烧制陶粒的化学组成范围内,SiO2的质量分数接近于48%的下限值,具备烧制污泥陶粒的基本条件;污泥陶粒的抗压强度随着表观密度的增加而增大,烧制温度对污泥陶粒的抗压强度和表观密度产生明显影响,在1 075 ℃时烧制的污泥陶粒具有最大的抗压强度(71.7 MPa)和表观密度(2.45 g/cm3),污泥陶粒的吸水率随烧制温度的增加而减小.

[1] 翁焕新.污泥无害化、减量化、资源化处理新技术[M].北京:科学出版社,2009: 73-74.
[2] MOHAMMED H A S, ISMAIL M M, RAHMAN A M B. Use of sewage sludge ash in asphaltic paving mixes in hot regions [J]. Construction and Building Materials, 1995, 9 (1): 19-23.
[3] WANG Kuensheng, CHIOU Ingjia, CHEN Chingho, et al. Lightweight properties and pore structure of foamed material made from sewage sludge ash [J]. Construction and Building Materials, 2005, 19 (8): 627-633.
[4] PAN Shihcheng, TSENG Dyihwa, LEE Chihchiang, et al. Influence of the fineness of sewage sludge ash on the mortar properties [J]. Cement and Concrete Research, 2003, 33 (11): 1749-1754.
[5] NAKOUZI S.A novel approach to paint sludge recycling [J].Journal of Material Research,1998,13(1): 53-60.
[6] 吴清仁,吴善淦.生物建材与环保[M].北京:化学工业出版社,2003: 215-225.
[7] 吴清仁,吴善淦,邢益和,等.一种利用污水处理厂生物污泥烧制粘土陶粒的方法:中国,2114938.0 [P].2004-10-20.
WU Qingren, WU Shangan, XING Yihe, et al. A method for sintering haydite by using sewage sludge: China, 2114938.0 [P]. 2004-10-20.
[8] 中国大洋矿产资源研究开发协会,青岛海洋地质研究所,核工业北京地质研究院.GB/T 20260—2006.海底沉积物化学分析方法[S].北京:中国标准出版社,2006.
China Ocean Mineral Resources R&D Association, Qingdao Institute of Marine Geology, CNNC Beijing Research Institute of Uranium Geology, et al. GB/T 20260—2006. Chemical analysis methods for marine sediment [S]. Beijing: Standards Press of China, 2006.
[9] 冶金工业部洛阳耐火材料研究所.GB 6900.2—1986.粘土、高铝质耐火材料化学分析方法重量:钼蓝光度法测定二氧化硅量[S].北京:中国标准出版社,1986.
Ministry of Metallurgical Industry Luoyang Institute of Refractories. GB 6900.2—1986. Fireclay and highalumina refractories; Determination of silicon dioxide content; Gravimetricmolybdenum blue photometric method [S]. Beijing: Standards Press of China, 1986.
[10] 中国轻工业陶瓷研究所,九江出入境检验检疫局.GB/T 6297—2002.陶瓷原料差热分析方法[S].北京:中国标准出版社,2002.
Ceramic Research Institute of Light Industry of China, JiuJiang EntryExit Inspection and Quarantine Bureau. GB/T 6297—2002. Standard test method for differential thermal analysis of ceramic [S]. Beijing: Standards Press of China, 2002.
[11] CHIOU Ingjia, WANG Kuensheng, CHEN Chingho, et al. Lightweight aggregate made from sewage sludge and incinerated ash [J]. Waste Management, 2006, 26(12): 1453-1461.
[12] LIN Kaelong, CHIANG Kungyuh, LIN Dengfong. Effect of heating temperature on the sintering characteristics of sewage sludge ash [J]. Journal of Hazardous Materials, 2006, 128(2/3): 175-181.
[13] 王兴润,金宜英,杜欣,等.城市污水厂污泥烧制制陶粒的可行性研究[J].中国给水排水,2007,23(7): 11-15.
WANG Xingrun, JIN Yiying, DU Xin, et al. Feasibility research on sintering municipal sewage sludge for manufacturing haydite [J]. China Water and Wastewater, 2007, 23(7): 11-15.
[14] IGNACIO M, LUIS F, ARVALO, et al. Preparation and characterization of ceramic products by thermal treatment of sewage sludge ashes mixed with different additives [J]. Waste Management, 2007, 27(12): 1829-1844.
[15] 中国科学院上海硅酸盐研究所.陶瓷的力学性质[M].上海:上海科学技术文献出版社,1981: 323.
[16] 王兴润,金宜英,聂永丰,等.污泥制陶粒技术可行性分析与烧结机理研究[J].环境科学研究,2008, 21(6): 80-84.
WANG Xingrun, JIN Yiying, NIE Yongfeng, et al. Sintering characteristics and application research of sewage sludge in producing lightweight aggregate [J]. Research of Environmental Sciences, 2008, 21(6): 80-84.
[17] 中国建筑材料工业协会.GB/T 17431.2—1998.轻集料及其试验方法第2部:轻集料试验方法[S].北京:中国标准出版社,1999.
China Building Material Industry Association. GB/T 17431.2—1998. Lightweight aggregates and its test methodspart 2: test methods for lightweight aggregates [S]. Beijing: Standards Press of China, 1999.
[18] 石油大学(华东),北京石油勘探开发科学研究院,胜利石油管理局地质科学研究院.SY/T 6210—1996. 沉积岩中粘土矿物总量和常见非粘土矿物X射线衍射定量分析方法[S].北京:中国标准出版社,1996.
China University of Petroleum, Beijing Petroleum Exploration and Development Research, Shengli Petroleum Administrative Bureau Academy of Geological Sciences. SY/T 6210—1996. Total amount of cl

[1] FU Cheng-long, MA Hong-lei, CHI Yong, YAN Jian-hua, NI Ming-jiang. Study on migration and stability of total Cr
in tannery sludge by thermal hydrolysis treatment
[J]. J4, 2013, 47(9): 1631-1636.
[2] XIE Hao-hui, MA Hong-lei, CHI Yong, MA Zeng-yi. Bound water measurement methods and moisture distribution within sewage sludge[J]. J4, 2012, 46(3): 503-508.
[3] WANG Qin, YAN Jian-hua, PAN Xin-chao, CHI Yong, GAO Fei. Vitrification of MSWI fly ash using direct current double arc plasma[J]. J4, 2011, 45(1): 141-145.
[4] JIANG Xu-Guang, LI Chun-Yu, CHE Chong, SHU Kai, FU Juan-Juan. Migration characteristics of inorganic bromine during
incineration of medical waste
[J]. J4, 2010, 44(9): 1787-1792.
[5] MA Hua-Wen, WENG Huan-Xin. Effects of temperature and granule size on sludge drying characteristics[J]. J4, 2009, 43(09): 1661-1667.