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浙江大学学报(工学版)
浙江大学学报(工学版)  2021, Vol. 55 Issue (8): 1594-1606    DOI: 10.3785/j.issn.1008-973X.2021.08.021
化学工程     
火炸药光固化3D打印成型
谭博军(),陈斌,刘亚静,汪伟,李子森,汪营磊(),肖川
1. 西安近代化学研究所，陕西 西安 710065
2. 中国兵器工业新技术推广研究所，北京 100089
3. 中国兵器科学研究院，北京 100089
Photocurable 3D printing molding of propellants and explosives
Bo-jun TAN(),Bin CHEN,Ya-jing LIU,Wei WANG,Zi-sen LI,Ying-lei WANG(),Chuan XIAO
1. Xi’an Modern Chemistry Research Institute, Xi’an 710065, China
2. Advanced Technology Generalization Institute of China North Industries Group, Beijing 100089, China
3. Academy of Ordnance Science, Beijing 100089, China
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摘要：

针对发射药、推进剂、炸药光固化3D打印技术，按照光固化3D打印技术的特点和应用方向，综述火炸药光固化3D打印技术的研究进展. 概述立体光固化成型技术、数字光处理技术、连续液面制造技术的成型原理以及工艺特点，分析光固化3D打印火炸药研究存在的问题，提出光固化3D打印火炸药采用新型黏合剂的重要性，总结光固化黏合剂的发展方向和趋势，并对火炸药光固化3D打印技术发展方向进行预测. 指出火炸药光固化3D打印技术应按照火炸药的应用背景，对光固化3D打印火炸药用含能黏合剂设计与制备、黏合剂与固体填料表界面作用、工艺适配性、性能精细化表征进行系统化研究，为光固化3D打印技术在火炸药中的应用提供参考.
关键词： 光固化3D打印;  研究进展;  火炸药;  成型原理;  黏合剂    
Abstract:

The research status of photocuring 3D printing technology in gun propellant, propellants and explosives were summarized according to the technical characteristics and application directions. The principle and process characteristics of stereo lithography apparatus, digital light process and continuous liquid interface production were generalized. The problems in the research of photocurable 3D printing molding of propellants and explosives were analyzed, the importance of new adhesives for photocurable 3D printing molding of propellants and explosives was put forward, and the development direction and trend of photocurable adhesive were summarized. It is pointed out that the photocuring 3D printing technology of propellants and explosives should be systematically studied according to the application background, and the design and preparation of energetic adhesive, the interaction between adhesive and solid packing surface, the process adaptability of formulations and the fine characterization of performance should be systematically studied to provide reference for the application of photocurable 3D printing technology in propellants and explosives.
Key words: photocurable 3D printing    development    propellants and explosives    molding principle    adhesive material
收稿日期: 2021-04-01 出版日期: 2021-09-01
CLC:  O 63  
基金资助: 国家自然科学基金资助项目（21875185，22005238，22105156）
通讯作者: 汪营磊     E-mail: tanbj204@163.com;wangyl204@163.com
作者简介: 谭博军（1992—），男，博士. oricid.org/0000-0002-2634-6494. E-mail： tanbj204@163.com
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谭博军
陈斌
刘亚静
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李子森
汪营磊
肖川

引用本文:

谭博军,陈斌,刘亚静,汪伟,李子森,汪营磊,肖川. 火炸药光固化3D打印成型[J]. 浙江大学学报(工学版), 2021, 55(8): 1594-1606.

Bo-jun TAN,Bin CHEN,Ya-jing LIU,Wei WANG,Zi-sen LI,Ying-lei WANG,Chuan XIAO. Photocurable 3D printing molding of propellants and explosives. Journal of ZheJiang University (Engineering Science), 2021, 55(8): 1594-1606.

链接本文:

https://www.zjujournals.com/eng/CN/10.3785/j.issn.1008-973X.2021.08.021    或    https://www.zjujournals.com/eng/CN/Y2021/V55/I8/1594

图 1  光固化3D打印黏合体系的组成
图 2  光固化成型原理
图 3  SLA技术的成型原理
图 4  DLP技术的成型原理
图 5  CLIP技术的成型原理
技术名称 光固化方式 打印速度 主要优点 主要缺点
SLA 扫描式 慢 性价比高 打印速度慢
DLP 面投影式 较快 分辨率比SLA高 质量受限于
像素尺寸
CLIP 掩膜图像投影式 最快 速度最快 价格高昂；
对光敏树脂要求高
表 1  SLA、DLP和CLIP技术对比
图 6  TNO公司打印得到的发射药
图 7  超多孔发射药
图 8  多孔圆盘推进剂的评估测试试验
图 9  HTPB复合推进剂代料体系的配制以及成型试验
图 10  HTPB复合推进剂代料体系的成型试验效果图以及打印药条的燃烧图
图 11  使用Gau-8测试枪进行MPD评估测试
图 12  MEMS推进芯片药室及装药原理
图 13  制造化学芯片快速成型系统功能图
图 14  许迪[46]所提光固化黏合体系的主要组分
图 15  含能芯片快速成型软件的体系结构图
图 16  朱锦珍[47]所提光固化黏合体系的主要组分
图 17  喷墨成型系统机构图
图 18  王建[48]所提光固化黏合体系的主要组分
图 19  邢宗仁[49]所提含能油墨配方的主要组分
图 20  模拟图、打印效果图和点火示意图
图 21  王景龙[50]所提光固化黏合体系的主要组分
图 22  细化RDX的表面形态图
图 23  姚艺龙等[51]所提光固化黏合体系的主要组分
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