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J4  2013, Vol. 47 Issue (12): 2170-2175    DOI: 10.3785/j.issn.1008-973X.2013.12.015
尹红, 俞安, 盛财平, 袁慎峰, 陈志荣
浙江大学 化学工程与生物工程学系,浙江 杭州 310027
Study on reaction products of vitamin A in tributyrin under heating
YIN Hong, YU An, SHENG Cai-ping, YUAN Shen-feng, CHEN Zhi-rong
Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
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Vitamin A acetate (VAA) was heated at six different temperatures in tributyrin in the absence of oxygen and light in order to investigate the storage stability of vitamin A. HPLC with diode array detector (DAD) and HPLC with mass spectrometer (MS) were applied to analyze the structures of the by-products, and the mass fraction of VAA and various by-products were given with the time progressing as well. It is found that at low temperatures, the isomerization plays a leading role and VAA isomers are the main products; while at high temperatures, three reactions, namely isomerization, dehydration and dimerization, take place in this process, and VAA isomers, anhydrovitamin A and vitamin A dimers are the main products.

出版日期: 2013-12-01
:  TQ 466.1  


通讯作者: 袁慎峰,男,副教授.     E-mail:
作者简介: 尹红(1971—),女,副教授,从事反应工程和应用化学教学科研工作.E-mail:
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尹红, 俞安, 盛财平, 袁慎峰, 陈志荣. 三丁酸甘油酯中维生素A热处理反应产物研究[J]. J4, 2013, 47(12): 2170-2175.

YIN Hong, YU An, SHENG Cai-ping, YUAN Shen-feng, CHEN Zhi-rong. Study on reaction products of vitamin A in tributyrin under heating. J4, 2013, 47(12): 2170-2175.


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