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浙江大学学报(工学版)
JOURNAL OF ZHEJIANG UNIVERSITY (ENGINEERING SCIENCE)
Materials Engineering     
Fabrication of inverted opal photonic crystal based on zeolite imidazolate frameworks
YANG Can1, GAO Feng yu1, CHEN Lu jian1,2, CUI Yuan jing2, QIAN Guo dong2
1.Department of Electronic Engineering, Xiamen University, Xiamen 361005, China; 2. State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027, China
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Abstract  

New composite inverted opal photonic crystals were fabricated combining zeolite imidazolate frameworks (ZIFs) with inverted opal photonic crystals. Silicon dioxide (SiO2) inverted opal photonic crystals and polystyrene (PS) inverted opal photonic crystals were used as support, and their surface was modified with carboxyl groups. The carboxyl groups prompt the adhesive of ZIF 8 by coordinating to the apical sites of the Zn2 units, and make ZIF 8 films grow on the two kinds of inverted opal photonic crystals successfully. Results showed that ZIF 8 films maintained the crystalline nature of ZIF 8. They were of nice connection with the inverted photonic crystals and the growth of which was uniform and dense. The composite inverted opal photonic crystals had a shift in photonic band gaps comparing to the original inverted photonic crystal, which accorded well with the predict results.

Published: 01 April 2016
CLC:  O 648  
  O 782  
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YANG Can, GAO Feng yu, CHEN Lu jian, CUI Yuan jing, QIAN Guo dong. Fabrication of inverted opal photonic crystal based on zeolite imidazolate frameworks. JOURNAL OF ZHEJIANG UNIVERSITY (ENGINEERING SCIENCE), 2016, 50(4): 799-.

URL:

http://www.zjujournals.com/eng/10.3785/j.issn.1008-973X.2016.04.027     OR     http://www.zjujournals.com/eng/Y2016/V50/I4/799


基于沸石咪唑酯的反蛋白石光子晶体制备研究

通过将沸石咪唑酯骨架材料(ZIFs)与反蛋白石光子晶体相结合,制备新型反蛋白石光子晶体.以二氧化硅（SiO2）反蛋白石光子晶体与聚苯乙烯（PS）反蛋白石光子晶体作为载体,通过在表面修饰羧基官能团的方式,使ZIF 8中的锌离子与反蛋白石光子晶体表面的羧基配位连接,成功地在2种反蛋白石光子晶体表面上生长了ZIF 8薄膜,制备了2种复合型反蛋白石光子晶体.结果表明,ZIF 8薄膜保持了ZIF 8原有的晶体特性,在反蛋白石光子晶体上覆盖均匀致密,表现出了较好的结合力.复合型反蛋白石光子晶体的光子带隙与原始的反蛋白石光子晶体相比产生了移动,与预测相符.

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