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浙江大学学报(工学版)
浙江大学学报(工学版)
能源工程     
加湿温度对燃料电池性能影响的实验研究
王世学1,齐贺2
1. 天津大学 内燃机燃烧学国家重点实验室, 天津 300072；2. 天津大学 机械工程学院, 天津300072
Experimental study on  PEM fuel cell under conditions of different humidification temperatures
WANG Shi xue1, QI He2
1. State Key Laboratory of Engines, Tianjin University, Tianjin 300072, China;2. School of Mechanical Engineering, Tianjin University, Tianjin 300072, China
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摘要：

针对膜电极有效面积为25 cm2的质子交换膜燃料电池(PEMFC)单体以0.8 A/cm2的电流密度恒流放电过程中，阴阳极反应气体加湿温度不同时电池性能的变化，通过监测电池温度及阴阳极流场入口压力，探讨在不同加湿条件下，阴极入口压力与电池性能之间的关系.实验结果表明，空气加湿温度显著地影响阴极入口压力的高低与稳定性，以及阴极压力与电池输出电压的相关性.同时，相较于阳极氢气，对阴极空气的加湿更有利于燃料电池的稳定运行.
Abstract:

A single PEM fuel cell with the active membrane electrode area of 25 cm2 was tested under the constant current mode of 0.8 A/cm2, in order to clarify different effects of humidification temperature for hydrogen and air on the performance of fuel cell.  The relation between inlet pressure of cathode and cell performance was discussed for different conditions of humidification, by monitoring the temperature of fuel cell and the inlet pressure of flow fields during the tests. Results show that the humidification temperature of air  significantly affects the magnitude and stability of inlet pressure in cathode, and the relativity of cathode pressure and output voltage of cell. In comparison with hydrogen in anode, humidify to air in cathode is more effective for the stable operation of fuel cell.
出版日期: 2015-11-01
:  TM 911  
基金资助:

科技部国际合作项目（2013DFG60080）
作者简介: 王世学（1964-），男，教授，博导.主要从事传热传质、燃料电池方面研究.OREID:0000 0002 3098 3605.E-mail:wangshixue_64@tju.edu.cn.
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引用本文:

王世学,齐贺. 加湿温度对燃料电池性能影响的实验研究[J]. 浙江大学学报(工学版), 10.3785/j.issn.1008 973X.2015.11.022.

WANG Shi xue, QI He. Experimental study on  PEM fuel cell under conditions of different humidification temperatures. JOURNAL OF ZHEJIANG UNIVERSITY (ENGINEERING SCIENCE), 10.3785/j.issn.1008 973X.2015.11.022.

链接本文:

http://www.zjujournals.com/eng/CN/10.3785/j.issn.1008 973X.2015.11.022    或    http://www.zjujournals.com/eng/CN/Y2015/V49/I11/2193

［1］WANG Y, CHEN K S, MISHLER J, et al. A review of polymer electrolyte membrane fuel cells: technology, applications, and needs on fundamental research ［J］. Applied Energy, 2011, 88(4): 981-1007．
［2］刘朝玮,王保国,何小荣. 质子交换膜燃料电池研究及应用现状［J］. 现代化工,2004,24(9)：10-13．
LIU Chao wei, WANG Bao guo, HE Xiao rong. Review on proton exchange membrane fuel cell and its applications ［J］. Modern Chemical Industry, 2004, 24(9): 10-13．
［3］ YOUSFI STEINER N, MOOTGUY P, CANDUSSO D, et al. A review on PEM voltage degradation associated with water management: Impacts, influent factors and characterization ［J］. Journal of Power Sources, 2008, 183(1): 260-274．
［4］ 王文东,陈实,吴峰. 温度、压力和湿度对质子交换膜燃料电池性能的影响［J］. 能源研究与信息, 2003,19(1)：39-46．
WANG Wen dong, CHEN Shi, WU Feng. Effects of temperature, pressure and humidity on the performance of proton exchange membrane fuel cells ［J］. Energy Research and Information, 2003, 19(1): 39-46．
［5］ 谢晋,黄允千. 温度、湿度对质子交换膜燃料电池性能的影响［J］. 上海海事大学学报,2005,26(3)：60-63．
XIE Jin, HUANG Yun qian. Effects of temperature and humidity on the performance of proton exchange membrane fuel cells ［J］. Journal of Shanghai Maritime University, 2005, 26(3): 60-63．
［6］胡桂林, 樊建人. 交指状流场质子交换膜燃料电池的数值分析［J］. 浙江大学学报：工学版,2009,43(6)：1147-1151．
HU Gui lin, FAN Jian ren. Numerical analysis of proton exchange membrane fuel cell with interdigitated flow fields ［J］. Journal of Zhejiang University ： Engineering Science, 2009, 43(6): 1147-1151．
［7］WONG K H, LOO K H, LAI Y M, et al. A theoretical study of inlet relative humidity control in PEM fuel cell ［J］. International Journal of Hydrogen Energy, 2011, 36(18): 11871-11885．
［8］ 丁刚强,罗志平,潘牧. 温度、流量和湿度对单蛇形流场PEMFC的影响［J］. 电池,2006,36(3)：178-180．
DING Gang qiang, LUO Zhi ping, PAN Mu. Effects of temperature, flux and humidity on the PEMFC with single serpentine flow field ［J］. Battery Bimonthly, 2006, 36(3): 178-180．
［9］ WANG L, HUSAR A, ZHOU T, et al. A parametric study of PEM fuel cell performances ［J］. International Journal of Hydrogen Energy, 2003, 28(11): 1263-1272．
［10］ HYUN D, KIM J. Study of external humidification method in proton exchange membrane fuel cell ［J］. Journal of Power Sources, 2004, 126(1): 98-103．
［11］ AMIRINEJAD M, ROWSHANZAMIR S, EIKANI M H. Effects of operating parameters on performance of a proton exchange membrane fuel cell ［J］. Journal of Power Sources, 2006, 161(2): 872-875．
［12］ LIN R, CAO C, MA J, et al. Optimizing the relative humidity to improve the stability of a proton exchange membrane by segmented fuel cell technology ［J］. International Journal of Hydrogen Energy, 2012, 37(4): 3373-3381．
［13］ SUN H, ZHANG G, GUO L J, et al. Effects of humidification temperatures on local current characteristics in a PEM fuel cell ［J］. Journal of Power Sources, 2007, 168(2): 400-407．
［14］ YAN Q, TOGHIANI H, CAUSEY H. Steady state and dynamic performance of proton exchange membrane fuel cells (PEMFCs) under various operating conditions and load changes ［J］. Journal of Power Sources, 2006, 161(1): 492-502．
［15］JEON D H, KIM K N, BAEK S M, et al. The effect of relative humidity of the cathode on the performance and the uniformity of PEM fuel cells ［J］. International Journal of Hydrogen Energy, 2011, 36(19): 12499-12511．
［16］JIAO K, HE P, DU Q, et al. Three dimensional multiphase modeling of alkaline anion exchange membrane fuel cell ［J］. International Journal of Hydrogen Energy, 2014, 39(11): 5981-5995．
［17］HASHIMASA Y, NUMATA T, MORIYA K, et al. Study of fuel cell structure and heating method: Development of JARIs standard single cell ［J］. Journal of Power Sources, 2006, 155(2): 182-189．
［18］HE W, LIN G, VAN NGUYEN T. Diagnostic tool to detect electrode flooding in proton exchange membrane fuel cells ［J］. AIChE Journal, 2003, 49(12): 3221-3228．
［19］BANERJEE R, HOWE D, MEJIA V, et al. Experimental validation of two phase pressure drop multiplier as a diagnostic tool for characterizing PEM fuel cell performance ［J］. International Journal of Hydrogen Energy, 2014, 39(31):17791-17801．
［20］HSIEH S S, HER B S, HUANG Y J. Effect of pressure drop in different flow fields on water accumulation and current distribution for a micro PEM fuel cell ［J］. Energy Conversion and Management, 2011, 52(2): 975-982．
［21］CHEN J. Dominant frequency of pressure drop signal as a novel diagnostic tool for the water removal in proton exchange membrane fuel cell flow channel ［J］. Journal of Power Sources, 2010, 195(4): 1177-1181．
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