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浙江大学学报（理学版）
浙江大学学报（理学版）  2016, Vol. 43 Issue (4): 411-415    DOI: 10.3785/j.issn.1008-9497.2016.04.006
化学     
不同结构C8烃在HZSM-5分子筛上的吸附与裂化研究
范浙永1, 刘涛2, 包秀秀1, 费金华1
1. 浙江大学 催化研究所, 浙江省应用化学重点实验室, 浙江 杭州 310028;
2. 中国石油天然气股份有限公司 兰州化工 研究中心, 甘肃 兰州 730060
The adsorption and catalytic cracking of C8 hydrocarbons on HZSM-5 zeolite
FAN Zheyong1, LIU Tao2, BAO Xiuxiu1, FEI Jinhua1
1. Institute of Catalysis, Key Lab of Applied Chemistry of Zhejiang Province, Zhejiang University, Hangzhou 310028, China;
2. Petrochina Lanzhou Chemical Research Centre, Lanzhou 730060, China
 全文: PDF(766 KB)  
摘要： 研究了正辛烷、正辛烯、环辛烷和环辛烯4种不同结构C8烃在HZSM-5分子筛上的吸附及催化裂化性能.结果表明，烃分子的类型和尺寸影响其在分子筛上的吸附与转化性能，受分子筛孔道尺寸的限制，未能进入分子筛孔道的环辛烷没有发生吸附和催化裂化反应，而环辛烯分子通过与分子筛孔道中的极性表面和质子酸中心的强作用进入孔道，能进入分子筛孔道的正辛烷和正辛烯的催化裂化程度与其被吸附固定性能相一致.
关键词： 烃结构;  HZSM-5分子筛;  吸附;  脱附;  催化裂化    
Abstract: The performances of adsorption, desorption and catalytic cracking of several C8 hydrocarbons with different structures have been tested on HZSM-5 zeolie. Cyclooctane was not converted on the zeolite because its molecular size was larger than the pore size of the zeolite and could not enter into the pores of the zelite. However, cyclooctene which had the similar molecular size as cyclooctane showed higher adsorption and conversion, due to the double bond promoting via the polarity induction and acidic sites of the zeolite. Obviously, n-octane and n-octene with smaller molecular size could enter into the pores of HZSM-5 zelite and bring adsorption and conversion. Therefore, the adsorption and conversion of C8 hydrocarbons on HZSM-5 zelite can be affected by their structures and properties.
Key words: structure of hydrocarbon    HZSM-5 zeolite    adsorption    desorption    catalytic cracking
收稿日期: 2015-07-09 出版日期: 2016-04-28
CLC:  O621  
基金资助: 国家973计划项目（2013CB228104）；中国石油天然气股份有限公司重大专项（10-01A-01-01-01）.
通讯作者: 费金华,E-mail:jhfei@zju.edu.cn.     E-mail: jhfei@zju.edu.cn
作者简介: 范浙永(1989-),ORCID:http://orcid.org/0000-0003-2551-3470,男,硕士研究生,主要从事烃类催化裂化研究.
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引用本文:

范浙永, 刘涛, 包秀秀, 费金华. 不同结构C8烃在HZSM-5分子筛上的吸附与裂化研究[J]. 浙江大学学报（理学版）, 2016, 43(4): 411-415.

FAN Zheyong, LIU Tao, BAO Xiuxiu, FEI Jinhua. The adsorption and catalytic cracking of C8 hydrocarbons on HZSM-5 zeolite. Journal of ZheJIang University(Science Edition), 2016, 43(4): 411-415.

链接本文:

https://www.zjujournals.com/sci/CN/10.3785/j.issn.1008-9497.2016.04.006    或    https://www.zjujournals.com/sci/CN/Y2016/V43/I4/411

[1] CORMA A,PLANELLES J.The role of different types of acid site in the cracking of alkanes on zeolite catalysts[J]. Journal of Catalysis,1985,93:30-37.
[2] WIELLERS A F H, VAAKAM P M.Relation between properties and performance of zeolites in paraffin cracking[J]. Journal of Catalysis,1991,127:51-66.
[3] RANE N, KERSBULCK M, SANTEN R A, et al. Cracking of n-heptane over Bronsted acid sites and Lewis acid Ga sites in ZSM-5 zeolite[J]. Microporous and Mesoporous Materials,2008,110:279-291.
[4] LIU P, ZHANG Z, JIA M. ZSM-5 zeolites with different SiO2/Al2O3 ratios as fluid catalytic cracking catalyst additives for residue cracking[J]. Chinese Journal of Catalysis,2015,36:806-812.
[5] JUNG J S, KIM T J, SEO G. Catalytic cracking of n-octane over zeolites with different pore structures and acidities[J]. Korean Journal of Chemical Engineering,2004,21:777-781.
[6] RAYBAUD P, PATRIGEON A, TOULHOAT H. The origin of the C7-hydroconversion selectivities on Y, beta, ZSM-22, ZSM-23, and EU-1 zeolites[J]. Journal of Catalysis,2001,197:98-112.
[7] BABITZ S M, WILLIAMS B A, MILLER J T. Monomolecular cracking of n-hexane on Y, MOR, and ZSM-5 zeolites[J]. Applied of Catalysis A: General,1999,179:71-86.
[8] MIYAJI A, IWASE Y, NISHITOBA T. Influence of zeolite pore structure on product selectivities for protolysis and hydride transfer reactions in the cracking of n-pentane[J]. Physical Chemistry Chemical Physics,2015,17:5014-5032.
[9] 王亚明.超微粒催化材料对松节油的择形催化作用[D].昆明:昆明理工大学,1999. WANG Yaming. Shape Selectivity Catalysis of Turpentine by Ultrafine Catalysts[D]. Kunming:Kunming University of Science and Technology,1999.
[10] 梅东海,李以圭,陆九芳.H型气体水合物结构稳定性的分子动力学模拟[J].化工学报,1998,49(6):662-670. MEI Donghai, LI Yigui, LU Jiufang. Molecular dynamics simulation of structure and stability of H type gas hydrate[J]. Journal of Chemical Industry and Engineering,1998,49(6):662-670.
[11] NGUYEN C M, DE MOOR B A, REYNIERS M, et al. Isobutene protonation in HFAU, HMOR, HZSM-5, and HZSM-22[J]. Journal of Physical Chemistry C,2012,116:18236-18249.
[12] VAN KONINGSVELD H, JANSEN J C. Single-crystal structure analysis of zeolite H-ZSM-5 loaded with naphthalene[J]. Microporous Material,1996,6(3):159-167.
[13] HAVENGA E A, HUANG Y. A study of binary adsorption of aromatics in completely siliceous zeolite ZSM-5 by FT-Raman spectroscopy[J]. Journal of Physical Chemistry,2005,109:18031-18036.
[14] KISSIN Y V. Chemical mechanisms of catalytic cracking over solid acidic catalysts: Alkanes and alkenes[J]. Catalysis Reviews,2001,43(1/2):85-146.
[15] WILLIAMS B A, BABITZ S M, MILLER J T.The roles of acid strength and pore diffusion in the enhanced cracking activity of steamed Y zeolites[J]. Applied Catalysis A: General,1999,177:161-175.
[16] 计海涛,龙军,李正.烯烃催化裂解的反应行为[J].石油学报:石油加工,2008,24(6):630-633. JI Haitao, LONG Jun, LI Zheng. Cracking performance of olefins on zeolite catalyst[J]. ACTA Petrolei Sinica: Petroleum Processing Section,2008,24(6):630-633.
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