Please wait a minute...
Journal of ZheJiang University (Engineering Science)  2025, Vol. 59 Issue (4): 863-869    DOI: 10.3785/j.issn.1008-973X.2025.04.022
    
Reduction of near membrane interface polarization phenomena in membrane distillation through flow channel disturbance
Jiaqi SUN(),Yaoling ZHANG,Fei GUO*()
School of Energy and Power Engineering, Dalian University of Technology, Dalian 116024, China
Download: HTML     PDF(1139KB) HTML
Export: BibTeX | EndNote (RIS)      

Abstract  

Polarization phenomena near the membrane interface directly reduce the vapor pressure difference on both sides of the membrane, thereby decreasing the transmembrane flux of membrane distillation. The flow-disturbing pillars were used to disturb the feed flow near the membrane interface in a contactless way. The influence and mechanism of parameters such as the isolated flow-disturbing pillar and the arrangements of multiple flow-disturbing pillars on flow disturbance and transmembrane mass transfer were studied. Experimental results show that flow channel disturbance can increase the transmembrane flux of air gap membrane distillation by more than 20% when the feed temperature is 70 ℃ and the feed flow rate is 0.2 L/min. Numerical simulation was used to analyze the influence of different flow-disturbing pillar arrangements on the feed flow state near the membrane interface region, and the pressure drop variations along the flow channel were studied. Results show that the flow-disturbing pillars not only effectively enhance the disorder of the feed flow near the membrane interface, but also break and reduce the polarization phenomena of the membrane distillation, without significantly increasing the pressure drop along the flow channel.



Key wordsmembrane distillation      near membrane interface      flow channel disturbance      polarization phenomena      transmembrane flux     
Received: 20 February 2024      Published: 25 April 2025
CLC:  TP 393  
Corresponding Authors: Fei GUO     E-mail: sunjiaqizg@mail.dlut.edu.cn;feiguo@dlut.edu.cn
Cite this article:

Jiaqi SUN,Yaoling ZHANG,Fei GUO. Reduction of near membrane interface polarization phenomena in membrane distillation through flow channel disturbance. Journal of ZheJiang University (Engineering Science), 2025, 59(4): 863-869.

URL:

https://www.zjujournals.com/eng/10.3785/j.issn.1008-973X.2025.04.022     OR     https://www.zjujournals.com/eng/Y2025/V59/I4/863


基于流道扰流的膜蒸馏近膜界面极化现象抑制

近膜界面的极化现象会直接降低膜两侧蒸气压差,进而降低膜蒸馏的跨膜通量. 使用扰流柱对近膜界面料液进行非接触式扰动,研究孤立扰流柱、多扰流柱布置方式对扰流和跨膜传质的影响和机理. 实验结果表明,当料液湿度为70 ℃,流量为0.2 L/min时,流道扰流可使气隙式膜蒸馏的跨膜通量提高超过20%. 采用数值模拟方法分析不同扰流柱布置方式对近膜界面区域料液流动状态的影响以及流道沿程压力降的变化. 分析结果表明,在不明显提高流道的沿程压力降的情况下,扰流柱能够有效增强近膜界面区域料液流动的无序性,破坏和抑制膜蒸馏的极化现象.


关键词: 膜蒸馏,  近膜界面,  流道扰流,  极化现象,  跨膜通量 
Fig.1 Apparatus and materials for air gap membrane distillation experiment
Fig.2 Influence of adding one flow-disturbing pillar on feed flow state in flow channel
Fig.3 Feed flow state near membrane interface under various arrangements of flow-disturbing pillars
Fig.4 Experimental results of transmembrane flux of membrane distillation under various arrangements of flow-disturbing pillars
Fig.5 Relationship between membrane distillation channel design and pressure drop along flow channel
[1]   姜晓滨, 孙国鑫, 贺高红 高效膜蒸馏结晶过程的研究进展[J]. 化工学报, 2020, 71 (9): 3905- 3918
JIANG Xiaobin, SUN Guoxin, HE Gaohong Research progress of high-efficiency membrane distillation crystallization process[J]. CIESC Journal, 2020, 71 (9): 3905- 3918
[2]   郭智, 张新妙, 章晨林, 等 膜蒸馏过程强化及优化技术研究进展[J]. 化工进展, 2016, 35 (4): 981- 987
GUO Zhi, ZHANG Xinmiao, ZHANG Chenlin, et al Current research and technical progress in membrane distillation process intensification and optimization[J]. Chemical Industry and Engineering Progress, 2016, 35 (4): 981- 987
[3]   ALQSAIR U F, ALSHWAIREKH A M, ALWATBAN A M, et al Computational study of sweeping gas membrane distillation process: flux performance and polarization characteristics[J]. Desalination, 2020, 485: 114444
doi: 10.1016/j.desal.2020.114444
[4]   LOU J, VANNESTE J, DECALUWE S C, et al Computational fluid dynamics simulations of polarization phenomena in direct contact membrane distillation[J]. Journal of Membrane Science, 2019, 591: 117150
doi: 10.1016/j.memsci.2019.05.074
[5]   LOKARE O R, VIDIC R D Impact of operating conditions on measured and predicted concentration polarization in membrane distillation[J]. Environmental Science and Technology, 2019, 53 (20): 11869- 11876
doi: 10.1021/acs.est.9b04182
[6]   SHI D, GONG T, QING W, et al Unique behaviors and mechanism of highly soluble salt-induced wetting in membrane distillation[J]. Environmental Science and Technology, 2022, 56 (20): 14788- 14796
doi: 10.1021/acs.est.2c03348
[7]   YUN Y, MA R, ZHANG W, et al Direct contact membrane distillation mechanism for high concentration NaCl solutions[J]. Desalination, 2006, 188 (1/2/3): 251- 262
[8]   ANVARI A, AZIMI YANCHESHME A, KEKRE K M, et al State-of-the-art methods for overcoming temperature polarization in membrane distillation process: a review[J]. Journal of Membrane Science, 2020, 616: 118413
doi: 10.1016/j.memsci.2020.118413
[9]   SULEMAN M, ASIF M, JAMAL S A Temperature and concentration polarization in membrane distillation: a technical review[J]. Desalination and Water Treatment, 2021, 229: 52- 68
doi: 10.5004/dwt.2021.27398
[10]   ZHANG Z, ZHANG N, XIANG B, et al Numerical investigation on mass and heat transfer performance for novel vacuum membrane distillation modules enhanced by semicircular spacers[J]. International Journal of Thermal Sciences, 2023, 187: 108165
doi: 10.1016/j.ijthermalsci.2023.108165
[11]   CHANG H, HO C D, CHEN Y H, et al Enhancing the permeate flux of direct contact membrane distillation modules with inserting 3D printing turbulence promoters[J]. Membranes, 2021, 11 (4): 266
doi: 10.3390/membranes11040266
[12]   JEONG S, GU B, CHOI S, et al Engineered multi-scale roughness of carbon nanofiller-embedded 3D printed spacers for membrane distillation[J]. Water Research, 2023, 231: 119649
doi: 10.1016/j.watres.2023.119649
[13]   ZHANG Y, MU X, SUN J, et al Optimizing membrane distillation performance through flow channel modification with baffles: experimental and computational study[J]. Separations, 2023, 10 (9): 485
doi: 10.3390/separations10090485
[14]   ELHENAWY Y, ELMINSHAWY N A S, BASSYOUNI M, et al Experimental and theoretical investigation of a new air gap membrane distillation module with a corrugated feed channel[J]. Journal of Membrane Science, 2020, 594: 117461
doi: 10.1016/j.memsci.2019.117461
[15]   ZHANG Y, SUN J, GUO F Performance enhancement for membrane distillation by introducing insoluble particle fillers in the feed[J]. Desalination, 2023, 558: 116624
doi: 10.1016/j.desal.2023.116624
[16]   ZHAO S, FERON P H M, CHEN X, et al Gas flow enhanced mass transfer in vacuum membrane distillation[J]. Desalination, 2023, 552: 116434
doi: 10.1016/j.desal.2023.116434
[17]   DONG C, HUANG Y, LIN H, et al Performance intensification and anti-fouling of the two-phase flow enhanced direct contact membrane distillation for seawater desalination[J]. Desalination, 2022, 541: 116059
doi: 10.1016/j.desal.2022.116059
[18]   LIAO X, CHOU S, GU C, et al Engineering omniphobic corrugated membranes for scaling mitigation in membrane distillation[J]. Journal of Membrane Science, 2023, 665: 121130
doi: 10.1016/j.memsci.2022.121130
[19]   ZHANG Y, GUO F Mitigating near-surface polarizations in membrane distillation via membrane surface decoration[J]. Desalination, 2024, 579: 117507
doi: 10.1016/j.desal.2024.117507
[20]   BAZARGAN HARANDI H, HU J, ASADI A, et al Experimental and theoretical analysis of scaling mitigation for corrugated PVDF membranes in direct contact membrane distillation[J]. Journal of Membrane Science, 2023, 686: 122001
doi: 10.1016/j.memsci.2023.122001
[21]   段蓝翔, 陈佳明, 蔡景成, 等 基于纤维膜的膜蒸馏界面结晶及清洗再生[J]. 浙江大学学报: 工学版, 2022, 56 (10): 2104- 2108
DUAN Lanxiang, CHEN Jiaming, CAI Jingcheng, et al Interfacial crystal fouling and regeneration of fibrous membrane based membrane distillation[J]. Journal of Zhejiang University: Engineering Science, 2022, 56 (10): 2104- 2108
[22]   ANQI A E, ALREHILI M, USTA M, et al Numerical analysis of hollow fiber membranes for desalination[J]. Desalination, 2016, 398: 39- 51
doi: 10.1016/j.desal.2016.07.019
[1] Lan-xiang DUAN,Jia-ming CHEN,Jing-cheng CAI,Fei GUO. Interfacial crystal fouling and regeneration of fibrous membrane based membrane distillation[J]. Journal of ZheJiang University (Engineering Science), 2022, 56(10): 2104-2108.