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J4  2012, Vol. 46 Issue (4): 590-598    DOI: 10.3785/j.issn.1008-973X.2012.04.003
PCDD/F distribution characteristics in soil samples from
urban areas of Hangzhou city
XIAO Pei-lin1,2, LU Sheng-yong1, WANG Qi1, WANG Fei1, YAN Jian-hua1
1. Institute for Thermal Power Engineering, Zhejiang University, Hangzhou 310027, China;
2. School of Mechanical Engineering, University of South China, Hengyang 421001, China
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The concentrations of 17 polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) congeners as well as tetra-to-octahomologues were determined in 8 soils in the old industrial area, 5 soils in the new industrial area and 2 soils in the tourism area from Hangzhou. The levels of PCDD/Fs in urban soils were primarily obtained. The ITEQ values of soils in old industrial area ranged 0.65~41.75 pg/g with average 12.73 pg/g, which is higher than the other two areas. The I-TEQ values of soils in the new industrial area and tourism area ranged (average) 0.61~1.33 pg/g (1.07 pg/g) and 1.53~2.11 pg/g (1.81 pg/g), respectively. The analysis of 17 congeners shows that OCDD accounts for 33.6%, which is the major contributor to total I-TEQ in the soils of old industrial area. This is because the OCDD is more stable than other congeners in the environment, which indicates that OCDD is the main congener emission of dioxin in the old industrial area.

Published: 17 May 2012
CLC:  X 833  
Cite this article:

XIAO Pei-lin, LU Sheng-yong, WANG Qi, WANG Fei, YAN Jian-hua. PCDD/F distribution characteristics in soil samples from
urban areas of Hangzhou city. J4, 2012, 46(4): 590-598.

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采集了杭州市城北老工业区土壤样品(8个)、新工业区土壤样品(5个)和旅游区土壤样品(2个),检测土样中17种二恶英有毒异构体的同系物毒性当量,初步获得了城区土壤二恶英的质量分数分布特性.分析结果显示,老工业区土壤的二恶英质量分数较高,毒性当量ITEQ为0.65~41.75 pg/g,平均值为12.73 pg/g.新工业区和旅游区的土壤二恶英质量分数较低,土壤中二恶英毒性当量分别为0.61~1.33 pg/g和1.53~2.11 pg/g,平均值分别为1.07 pg/g和1.81 pg/g.有毒同系物毒性当量分析显示,老工业区土壤毒性当量最大贡献者是八氯代二恶英(OCDD),占总量的33.6%,主要原因可能为OCDD在环境中较其他有毒同系物稳定,也说明老工业区的污染源以OCDD的排放为主.

[1] XIAO Changfa, CHEN S, LI Junzhao, et al. Association of HSP70 and genotoxic damage in lymphocytes of workers exposed to cokeoven emission [J]. Cell Stress and Chaperones, 2002, 7(4): 396-402.
[2] LOHMANN R, JONES K C. Dioxins and furans in air and deposition: a review of levels, behaviour and processes [J]. Science of the Total Environment, 1998, 219(1): 53-81.
[3] 李常清,陈左生,李伟,等.土壤中的二恶英类物质污染及其污染源[J].地球与环境,2004,32(2): 63-69.
LI Changqing, CHEN Zuosheng, LI Wei, et al. Source and level of dioxins in the soil environment [J]. Earth and Environment, 2004, 32(2): 63-69.
[4] YAN Jianhua, XU Mengxia, LU Shengyong, et al. PCDD/F concentrations of agricultural soil in the vicinity of fluidized bed incinerators of cofiring MSW with coal in Hangzhou, China [J]. Journal of Hazardous Materials, 2008, 151(2/3): 522-530.
[5] HARNER T, GREEN N J L, JONES K C. Measurements of octanolair partition coefficients for PCDD/Fs: a tool in assessing airsoil equilibrium status [J]. Environmental Science and Technology, 2000, 34(15): 3109-3114.
[6] DUARTEDAVIDSON R, SEWART A, ACLOCK R E, et al. Exploring the balance between sources, deposition, and the environmental burden of PCDD/Fs in the UK terrestrial environment: an aid to identifying uncertainties and research needs [J]. Environmental Science and Technology, 1997, 31(1): 1-11.
[7] SCHUHMACHER M, NADAL M, DOMINGO J L. Levels of PCDD/Fs, PCBs, and PCNs in soils and vegetation in an area with chemical and petrochemical industries [J]. Environmental Science and Technology, 2004, 38(7): 1960-1969.
[8] HARRAD S J, JONES K C. A source inventory and budget for chlorinated dioxins and furans in the unitedkingdom environment [J]. Science of the Total Environment, 1992, 126(1/2): 89-107.
[9] MAYSTRENKO V, KRUGLOV E, AMIROVA Z, et al. Polychlorinated dioxin and dibenzofuran levels in the environment and food from the republic of Bashkortostan, Russia [J]. Chemosphere, 1998, 37(9/10/11/12): 1699-1708.
[10] YAKE B, ROGOWSKI D, GOLDSTEIN L, et al. Dioxins in Washington State Soils [C]∥ Dioxin 2000: 20th International Symposium on Halogenated Environmental Organic Pollutants and POPS. Monterey: Organohalogen Compound, 2000: 342-345.
[11] 刘劲松,刘维屏,潘荷芳,等.农村简易垃圾焚烧炉周边土壤二恶英分布研究[J].浙江大学学报:工学版,2010,44(3): 601-605.
LIU Jinsong, LIU Weiping, PAN Hefang, et al. Distribution of PCDD/ Fs in soil samples in vicinity of a simply rural solid waste incinerator [J]. Journal of Zhejiang University: Engineering Science, 2010, 44(3): 601-605.
[12] 周志广,田洪海,李楠,等.北京市部分地区土壤中二噁英类物质污染水平初探[J].环境科学研究,2006, 19(6): 54-58.
ZHOU Zhiguang, TIAN Honghai, LI Nan, et al. Preliminary study on level and pattern of PCDD/PCDFs in soil in part of Beijing City [J]. Research of Environmental Science, 2006, 19(6): 54-58.
[13] ROTARD W, CHRISTMANN W, KNOTH W. Background levels of PCDD/F in soils og Germany [J]. Chemosphere, 1994, 29(9/10/11): 2193-2200.
[14] KUKUCKA P, KLANOVA J, SANKA M, et al. Soil burdens of persistent organic pollutants: their levels, fate and risk. Part II. are there any trends in PCDD/F levels in mountain soils? [J]. Environmental Pollution, 2009, 157(12): 3255-3263.
[15] CREASER C S, FERNANDES A R, AIHANDDAD A, et al. Survey of background levels of PCDDs &PCDFs in UK soils [J]. Chemosphere, 1989, 18(1/2/3/4/5/6): 767-776.
[16] 徐梦侠.城市生活垃圾焚烧厂二恶英排放的环境影响研究[D].杭州:浙江大学,2009: 67-72.
XU Mengxia. Environmental impact study on PCDD/Fs emissions from the municipal solid waste incineration plant [D]. Hangzhou: Zhejiang University, 2009: 67-72.
[17] OGURA I, MASUNAGA S, NAKANISHI J, et al. Congenerspecific characterization of PCDDs/PCDFs in atmospheric deposition: comparison of profiles among deposition, source, and environmental sink [J]. Chemosphere, 2001, 45(2): 173-183.
[18] BRZUZY L P, HITES R A. Global mass balance for polychlorinated dibenzo-p-dioxins and dibenzofurans [J]. Environmental Science and Technology, 1996, 30(6): 1797-1804.
[19] GREEN N J L, HASSANIN A, JOHNSTON A E, et al. Observations on historical, contemporary, and natural PCDD/Fs [J]. Environmental Science and Technology, 2004, 38(3): 715-723.
[20] LI Xiaodong, YAN Mi, CHEN Tong, et al. Levels of  PCDD/Fs in soil in the vicinity of a medical waste incinerator in China: the temporal variation during 20072009 [J]. Journal of Hazardous Materials, 2010, 179(1/2/3): 783-789.
[21] ALCOCK R E, SWEETMAN A J, JONES K C. A congenerspecific PCDD/F emissions inventory for the UK: do current estimates account for the measured atmospheric burden? [J]. Chemosphere, 2001, 43(2): 183-194.
[22] ANDERSSON A, OTTESEN R T. Levels of dioxins and  furans in urban surface soil in Trondheim, Norway [J]. Environmental Pollution, 2008, 152(3): 553-558.
[23] KAKIMOTO H, OKA H, HARADA Y, et al. Comparison of compositions of polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) in air and soil samples collected in Ishikawa [J]. Journal of Health Science, 2004, 50(1): 58-65.
[24] BRUBAKER W W, HITES R A. Polychlorinated dibenzopdioxins and dibenzofurans: gas phase hydroxyl radical reactions and related atmosphericremoval [J]. Environmental Science and Technology, 1997, 31(6): 1805-1810.

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