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J4  2012, Vol. 46 Issue (3): 476-481    DOI: 10.3785/j.issn.1008-973X.2012.03.014
Degradation characteristic of ABS resin manufacturing wastewater
using different  advanced oxidation processible
LAI Bo1,2, ZHOU Yue-xi2, YANG Ping1, QIN Hong-ke2, 3, PANG Cui-cui2, 3, LIAN Yu2, 3
1. School of Architecture and Environment, Sichuan University, Chengdu 610065, China;
2. Research Center of Water Pollution Control Technology, Chinese Research Academy of Environmental Sciences,
Beijing 100012, China; 3. College of Urban Construction, Hebei University of Engineering, Handan 056038,  China
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Different advanced oxidation processible (AOPs) was used to pretreat acrylonitrile-butadiene-styrene (ABS) resin manufacturing. Based on the qualitative analysis for the typical pollutants of ABS resin wastewater, the typic compounds of the effluent of different pretreatment were determined and analyzed by gas chromatography mass spectrometry (GC-MS), and the influence of different AOPs to the degradation or transformation of toxic nonbiodegradable typical pollutants was discussed.The results show that the wastewater contains about 10 typical pollutants which are mainly benzene series and organic nitriles, and the relative mass fraction of benzene series are the highest and account for 75.3% of total organic matter. The oxidative degradation capability of Fenton reagent was much stronger than that of the other two methods, and there are only two kinds of small amounts of organic nitriles in the effluent. Therefore, the Fenton reagent method is the best pretreatment method for ABS resin wastewater.

Published: 01 March 2012
CLC:  X 783.2  
Cite this article:

LAI Bo, ZHOU Yue-xi, YANG Ping, QIN Hong-ke, PANG Cui-cui, LIAN Yu. Degradation characteristic of ABS resin manufacturing wastewater
using different  advanced oxidation processible. J4, 2012, 46(3): 476-481.

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为了优化得出丙烯腈-苯乙烯-丁二烯的聚合物(ABS)生产废水的最佳预处理方法,采用不同的高级氧化法处理该废水.在定性分析ABS废水中特征污染物的基础上,采用气质联用色谱检测分析经不同高级氧化法处理后出水中主要特征污染物的变化, 研究不同高级氧化法对废水中有毒特征污染物的降解特性.结果表明:ABS树脂生产废水中含有约10种特征污染物,主要为苯系物和有机腈类污染物,其中苯系物的相对质量分数最高,占有机物总量的75.3%;芬顿试剂法的氧化降解能力最强,其处理后出水中仅残留2种少量的有机腈类化合物,即芬顿法为ABS废水的最佳预处理方法.

[1] 王彬. ABS树脂生产工艺现状及发展趋势[J]. 炼油与化工, 2008, 19(2): 11-14.
WANG Bing. Status quo and development trend of ABS resin production process[J]. Refining and Chemical Industry, 2008, 19(2): 11-14.
[2] 陆书来, 罗丽宏, 何琳. ABS树脂技术概况和发展趋势[J]. 化工科技, 2003, 11(5): 55-59.
LU Shulai, LUO Lihong, HE Lin. Technical survey and developing trend of ABS[J]. Science & Technology in Chemical Industry, 2003, 11(5): 55-59.
[3] 苏宏, 张晓杰, 王德义, 等. ABS树脂生产废水处理工程实践[J]. 环境工程, 2004, 22(4): 91-92.
SU Hong, ZHANG Xiaojie, WANG Deyi, et al. Practice of treating wastewater for production of ABS resin[J]. Environmental Engineering, 2004, 22(4): 91-92.
[4] 赵东风, 刘发强, 蒋文庆,等. 我国ABS树脂工业废水治理技术综述[J]. 油气田环境保护, 2003, 13(2): 8-10.
ZHAO Dongfeng, LIU Faqiang, JIANG Wenqing, et al. Development and status of technology for sewage disposal in ABS resin production in China[J]. Environmental Protection of Oil & Gas Fields, 2003, 13(2): 8-10.
[5] LIN C, TSAI T Y, LIU J C. Enhanced biodegradation of petrochemical wastewater using ozonation and bac advanced treatment system[J]. Water Research, 2001, 35(3): 700-704.
[6] 李向富. ABS装置生产废水可生化性研究[J]. 化工环保, 2004, 24(增刊): 44-55.
LI Xiangfu. Biodegradability study for ABS resin wastewater[J]. Environmental Protection of Chemical Industry, 2004, 24(suppl.): 44-55.
[7] BOTALOVA O, JAN S, TOM F, et al. Identification and chemical characterization of specific organic constituents of petrochemical effluents[J]. Water Research, 2009, 43(15):3797-3812.
[8] WANG X Y, SHI W, WU J, et al. Reproductive toxicity of organic extracts from petrochemical plant effluents discharged to the Yangtze River, China[J]. Journal of Environmental Sciences, 2010, 22(2): 297-303.
[9] 赖波,周岳溪,宋玉栋,等.一种定性分析ABS生产废水中溶解性有机物的方法\
LAI Bo, ZHOU Yuexi, SONG Yudong,et al.The qualitative analysis method of the dissolved organic matter(DOM) for ABS wastewater\
[J\].Sepctrosc opy and Spectral Analysis, 2011,31(3):784-788.
[10] LAI P, ZHAO H Z, WANG C, et al. Advanced treatment of coking wastewater by coagulation and zerovalent iron processes[J]. Journal of Hazardous Materials, 2007, 147(1/2): 232-239.
[11] CHANG C N, LIN J G, CHAO A C. The pretreatment of acrylonitrile and styrene with the ozonation process[J]. Water Science and Technology, 1997, 36(2/3): 263-270.
[12] LI R X, YANG C P, CHEN H, et al. Removal of triazophos pesticide from wastewater with Fenton reagent[J]. Journal of Hazardous Materials, 2009, 167(2/3): 1028-1032.
[13] RODRIGUES C S D, MADEIRA L M, BOAVENTURA R A. Optimization of the azo dye Procion Red HEXL degradation by Fentons reagent using experimental design[J]. Journal of Hazardous Materials, 2009, 164(2/3): 987-994.
[14] 林泓胤. 三段式流化床生物程序处理高氮工业废水之程序研究[D]. 台湾: 国立成功大学, 2000: 87-176.
LIN Hongyin. The study of threestage biological fluidized bed process in treatment of resin manufacturing wastewater with highstrength nitrogenous compounds[D]. Taiwan: National Cheng Kung University, 2000: 87-176.
[15] CHANG J S, CHANG C Y, CHEN A C, et al. Longterm operation of submerged membrane bioreactor for the treatment of high strength acrylonitrilebutadienestyrene (ABS) wastewater: effect of hydraulic etention time[J]. Desalination, 2005, 191(1/2/3): 45-51.
[16] CHANG C Y, CHANG J S. Quantification of air stripping and biodegradation of organic removal in acrylonitrilebutadienestyrene (ABS) industry wastewater during submerged membrane bioreactor operation[J]. Desalination,2005, 191(1/2/3): 162-168.
[17] WANG R, CHEN C L, GRATZL J S. Dechlorination and decolorization of chloroorganics in pulp bleach plant E1 effluents by advanced oxidation processes[J]. Bioresource Technology, 2004, 94(3): 267-274.

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