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李雅卓1, 王广伟2, 金建余2, 蔡佩君1, 王晓萍1
1.浙江大学 现代光学仪器国家重点实验室,浙江 杭州 310027;2.飞利浦亚洲研究院,上海,200233
Research on characteristics and applications of novel all-solid-state electrode in two-electrode system
LI Ya-zhuo1, WANG Guang-wei2, JIN Jian-yu2, CAI Pei-jun1, WANG Xiao-ping1
1. State Key Laboratory for Modern Optical Instrumentation,Zhejiang University,Hangzhou 310027,China;2. Philips Research Asia – Shanghai, Lane 888, Tianlin Road, Shanghai, 200233, China
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In order to enhance the stability of two-electrode system detecting instrument, active carbon (AC) electrode with large surface area had been used as all-solid-state counter electrode in novel detecting instrument. After investigating the super capacitance property and potential stability of AC electrode, it had been served as counter electrode, together with Pt and glassy carbon working electrode to form a two-electrode water quality detecting instrument for hydrogen peroxide and lead ion determination, respectively. The detection results indicate that, the sensitivity, detection limit and detection range of this detecting instrument are all reach the detecting performance of conventional three-electrode system. Active carbon is of advantages as potential stable, chemical inertness, low cost, ease of use and maintenance, which makes the novel two-electrode water quality detecting instrument simpler with a high reliability and a promising application prospect.

出版日期: 2014-08-01
:  TH 832  

目: 浙江大学-飞利浦-埃因霍温科技大学智慧之桥项.

通讯作者: 王晓萍,女,教授     E-mail:
作者简介: 李雅卓(1983—),女,博士生,从事水质检测仪器科研工作. E-mail:
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李雅卓, 王广伟, 金建余, 蔡佩君, 王晓萍. 两电极体系新型全固态电极特性分析与应用[J]. 浙江大学学报(工学版), 10.3785/j.issn.1008-973X.2014.08.023.

LI Ya-zhuo, WANG Guang-wei, JIN Jian-yu, CAI Pei-jun, WANG Xiao-ping. Research on characteristics and applications of novel all-solid-state electrode in two-electrode system. JOURNAL OF ZHEJIANG UNIVERSITY (ENGINEERING SCIENCE), 10.3785/j.issn.1008-973X.2014.08.023.


[1] WINQUIST F, BJORKLUND R, KRANTZ-RULCKER C, et al. An electronic tongue in the dairy industry [J]. Sensors and Actuators B: Chemical, 2005, 111: 299-304.
[2] GHILANE J, HAPIOT P, and BARD A J. Metal/polypyrrole quasi-reference electrode for voltammetry in nonaqueous and aqueous solutions [J]. Analytical chemistry, 2006, 78(19): 6868-6872.
[3] LEE H J, LAGGER G, PEREIRA C M, et al. Amperometric tape ion sensors for cadmium (II) ion analysis [J]. Talanta, 2009, 78(1): 66-70.
[4] WINQUIST F, KRANTZ-RULCKER C, OLSSON T, et al. Measurements of cadmium in soil extracts using multi-variate data analysis and electrochemical sensors [J]. Precision Agriculture, 2009, 10(3): 231-246.
[5] 魏佳莉, 章颖强, 李雅卓,等. 基于两电极体系的水质检测分析平台设计 [J]. 传感技术学报. 2012, 25(10): 1327-1332.
WEI Jia-li, ZHANG Ying-qiang, LI Ya-zhuo, et al. The design of a inspection and analysis platform of aqueous solution based on two-electrode system [J]. Chinese journal of sensors and actuators, 2012, 25(10): 1327-1332.
[6] WINQUIST F, OLSSON T, and ERIKSSON M. Multicomponent analysis of drinking water by a voltammetric electronic tongue [J]. Analytica chimica acta, 2011, 683(2): 192-197.
[7] RUCH P W, CERICOLA D, HAHN M, et al. On the use of activated carbon as a quasi-reference electrode in non-aqueous electrolyte solutions [J]. Journal of Electroanalytical Chemistry, 2009, 636(1): 128-131.
[8] 甘琦,周昕,赵斌元,等.成型活性炭的制备研究进展[J].材料导报.2006, 20(1): 61-63.
GAN Qi, ZHOU Xin, ZHAO Bing-yuan, et al. The advance of research on formed activated carbon preparation [J]. Material Review, 2006, 20(1): 61-63.
[9] PELL W G, CONWAY B E. Voltammetry at a de Levie brush electrode as a model for electrochemical supercapacitor behaviour [J]. Journal of Electroanalytical Chemistry, 2001, 500(1): 121-133.
[10] TAKATSY A, CSOKA B, NAGY L, et al. Periodically interrupted amperometry at membrane coated electrodes: A simplified pulsed amperometry [J]. Talanta, 2006, 69(1): 281-285.
[11] 于春梅 and 顾海鹰. 电化学预处理玻碳电极示差脉冲伏安法测定水中痕量铅 [J]. 理化检验:化学分册. 2010, 46(5): 525-527.
YU Chun-mei, GU Hai-ying. Determination of trace amount of lead in water by differential pulse voltammetry with chemically pretreated glassy carbon electrode [J]. Physical Testing and Chemical Analysis Part B: Chemical Analysis, 2010, 46(5): 525-527.

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