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浙江大学学报(农业与生命科学版)  2020, Vol. 46 Issue (3): 344-359    DOI: 10.3785/j.issn.1008-9209.2019.07.220
资源利用与环境保护     
淋洗条件下不同改良剂对浙江东部滨海盐碱土的改良效果
项子宸1,2(),修海峰3,马琨4,杨梢娜5,钟斌1,2,马嘉伟1,2,阮泽斌1,2,金文豪1,2,曹韩1,2,李雅倩1,2,金皋琪1,2,骆文轩1,2,柳丹1,2()
1.浙江农林大学, 亚热带森林培育国家重点实验室,杭州 311300
2.浙江农林大学环境与资源学院,浙江省土壤污染生物修复重点实验室,杭州 311300
3.岱山县北部开发建设管理处,浙江 岱山 316200
4.浙江浙农创投科技有限公司,杭州 311300
5.舟山市农林科学研究院,浙江 舟山 316000
Effect of different ameliorants on coastal saline-alkali soil in eastern Zhejiang under elution conditions
Zichen XIANG1,2(),Haifeng XIU3,Kun MA4,Shaona YANG5,Bin ZHONG1,2,Jiawei MA1,2,Zebin RUAN1,2,Wenhao JIN1,2,Han CAO1,2,Yaqian LI1,2,Gaoqi JIN1,2,Wenxuan LUO1,2,Dan LIU1,2()
1.State Key Laboratory of Subtropical Silviculture, Zhejiang A & F University, Hangzhou 311300, China
2.Key Laboratory of Soil Contamination Bioremediation of Zhejiang Province, School of Environment & Resource Sciences, Zhejiang A & F University, Hangzhou 311300, China
3.Northern Development and Construction Management Office of Daishan County, Daishan 316200, Zhejiang, China
4.Zhejiang Zhenong Agricultural Venture Technology Co. , Ltd. , Hangzhou 311300, China
5.Zhoushan Agriculture and Forestry Science Institute, Zhoushan 316000, Zhejiang, China
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摘要:

以滨海盐碱土为研究对象,选用脱硫石膏、过磷酸钙、生物炭、煤渣、聚马来酸酐5种改良剂,均分别按1%、1.5%、2%的梯度进行土柱淋洗试验,研究不同改良剂对浙江东部滨海盐碱土壤盐化特征的影响和对土壤质量的改良效果,从而筛选出适合该区域盐碱土改良的方案。结果表明:1)淋洗后的0~10 cm土层中,1%煤渣和2%聚马来酸酐对降低土壤pH的效果最佳,1.5%和2%生物炭对土壤电导率和含盐量的改良效果最显著,电导率较对照分别下降了93.75%、84.72%,含盐量较对照分别减少了55.44%、44.04%;2)所有改良剂均能有效降低土壤钠吸附比,尤其是2%煤渣、2%聚马来酸酐、1.5%过磷酸钙的效果最显著;3)能够较好地改良土壤化学性质、提高土壤肥力的改良剂是2%过磷酸钙、2%生物炭、2%聚马来酸酐;4)不同改良剂对盐基阳离子的淋洗效率存在差异,1%和1.5%过磷酸钙分别显著降低了土壤中的K、Ca2+和Mg2+含量,1%煤渣对土壤中Na、K淋洗效果最佳,1.5%和2%生物炭分别显著降低了土壤中Na+和Mg2+含量,1%和2%聚马来酸酐分别显著降低了土壤中Na和Ca2+、Mg2+含量。总体而言,施用1.5%聚马来酸酐、1.5%或2%生物炭对浙江东部滨海盐碱土壤脱盐培肥的改良效果最好。

关键词: 滨海盐碱土改良剂土壤肥力淋洗    
Abstract:

With the coastal saline-alkali soil as the research object, we carried out a soil column leaching experiment by using desulfurized gypsum, calcium superphosphate, biochar, coal cinder and polymaleic anhydride, all with concentration gradients of 1%, 1.5% and 2%, without adding soil ameliorants as controls. The effects of different ameliorants on salinization characteristics and soil quality of coastal saline-alkali soil in eastern Zhejiang were studied, and the suitable ameliorants for the improvement of coastal saline-alkali soil were selected. The results showed that: 1) In the 0-10 cm soil layer after eluting, 1% coal cinder and 2% polymaleic anhydride had the most significant improvement effect for decreasing soil pH. The improvements of soil electric conductivity (EC) and salinity were the most significant in the 1.5% and 2% biochar treatments. The EC decreased by 93.75% and 84.72% compared with the CK, and the salinity decreased by 55.44% and 44.04% compared with the CK. 2) Soil sodium adsorption ratio (SAR) decreased when the ameliorants were added, among which the 2% coal cinder, 2% polymaleic anhydride, 1.5% calcium superphosphate had the most significant improvement effect. 3) Soil chemical properties and fertility could be improved by the 2% calcium superphosphate, 2% biochar, 2% polymaleic anhydride. 4) Different ameliorants had different leaching efficiencies for salt-based cations: 1% and 1.5% calcium superphosphate could significantly reduce potassium, calcium and magnesium ion contents in the soil, respectively; 1% coal cinder had the best effect on sodium and potassium ion contents in the leaching soil; 1.5% and 2% biochars significantly reduced sodium and magnesium ion contents in the soil, respectively; and 1% and 2% polymaleic anhydride significantly reduced sodium and calcium, magnesium ion contents in the soil, respectively. In conclusion, 1.5% polymaleic anhydride, 1.5% or 2% biochar have the best effect of desalting and fertilizing on the coastal saline-alkali soil in eastern Zhejiang.

Key words: coastal saline-alkali soil    ameliorant    soil fertility    elution
收稿日期: 2019-07-22 出版日期: 2020-07-17
CLC:  S 156.2  
基金资助: 国家自然科学基金面上项目(31670617);浙江省科技厅重点研发计划(2015C03020-2);浙江农林大学学生科研训练项目(KX20180085);浙江省地方技术服务项目(H20190170)
通讯作者: 柳丹     E-mail: 2017703551009@zafu.edu.cn;liudan7812@aliyun.com
作者简介: 项子宸(https://orcid.org/0000-0003-3635-5498),E-mail:2017703551009@zafu.edu.cn
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项子宸
修海峰
马琨
杨梢娜
钟斌
马嘉伟
阮泽斌
金文豪
曹韩
李雅倩
金皋琪
骆文轩
柳丹

引用本文:

项子宸,修海峰,马琨,杨梢娜,钟斌,马嘉伟,阮泽斌,金文豪,曹韩,李雅倩,金皋琪,骆文轩,柳丹. 淋洗条件下不同改良剂对浙江东部滨海盐碱土的改良效果[J]. 浙江大学学报(农业与生命科学版), 2020, 46(3): 344-359.

Zichen XIANG,Haifeng XIU,Kun MA,Shaona YANG,Bin ZHONG,Jiawei MA,Zebin RUAN,Wenhao JIN,Han CAO,Yaqian LI,Gaoqi JIN,Wenxuan LUO,Dan LIU. Effect of different ameliorants on coastal saline-alkali soil in eastern Zhejiang under elution conditions. Journal of Zhejiang University (Agriculture and Life Sciences), 2020, 46(3): 344-359.

链接本文:

http://www.zjujournals.com/agr/CN/10.3785/j.issn.1008-9209.2019.07.220        http://www.zjujournals.com/agr/CN/Y2020/V46/I3/344

指标

Index

原土

Original soil

容重 Bulk density/(g/cm3)1.3
黏粒 Clay/%52.6
粉粒 Silt/%14.8
砂粒 Sand/%32.6
pH8.37±0.05
电导率 Electric conductivity/(mS/cm)5.34±0.15
含盐量 Salinity/%2.80±0.09
K/(g/kg)3.04±0.10
Ca2+/(g/kg)3.75±0.11
Na/(g/kg)5.10±0.14
Mg2+/(g/kg)2.28±0.18
碱解氮 Available N/(mg/kg)35.00±0.23
有效磷 Available P/(mg/kg)6.14±0.14
速效钾 Available K/(mg/kg)945.00±0.35
有机质 Organic matter/(g/kg)9.75±0.28
表1  供试土壤理化性质与离子组成

指标

Index

脱硫石膏

Desulfurized gypsum

过磷酸钙

Calcium superphosphate

煤渣

Coal cinder

生物炭

Biochar

聚马来酸酐

Polymaleic anhydride

pH7.32±0.212.06±0.113.88±0.196.07±0.080.76±0.23

电导率

Electric conductivity/(mS/cm)

2.47±0.103.43±0.050.89±0.121.37±0.036.84±0.67
有机碳 Organic carbon/(g/kg)4.94±0.662.32±0.6510.89±0.3920.04±0.4671.89±1.59
全氮 Total N/(g/kg)0.21±0.020.14±0.010.23±0.000.26±0.010.82±0.00
全磷 Total P/(g/kg)0.09±0.0040.57±0.280.38±0.011.30±0.122.80±0.03
K/(g/kg)0.77±0.019.87±1.1415.19±0.5264.66±4.65
Ca2+/(g/kg)48.23±8.1683.28±0.5427.94±3.9910.43±0.15
Na/(g/kg)1.46±0.161.94±0.137.28±0.5212.56±0.42
Mg2+/(g/kg)1.68±0.026.08±0.581.51±0.203.41±0.07
总铅 Total Pb/(mg/kg)15.33±1.3313.83±1.1812.17±0.2420.50±2.59
总锌 Total Zn/(mg/kg)56.50±0.7158.67±1.67126.33±8.49231.67±19.80
总铜 Total Cu/(mg/kg)13.17±0.715.33±0.4728.89±1.2636.17±1.18
总镉 Total Cd/(mg/kg)0.29±0.070.13±0.020.77±0.620.29±0.02
表2  改良剂性质

处理

Treatment

改良剂

Ameliorant

CK不添加
G11%脱硫石膏
G21.5%脱硫石膏
G32%脱硫石膏
L11%过磷酸钙
L21.5%过磷酸钙
L32%过磷酸钙
T11%生物炭
T21.5%生物炭
T32%生物炭
M11%煤渣
M21.5%煤渣
M32%煤渣
J11%聚马来酸酐
J21.5%聚马来酸酐
J32%聚马来酸酐
表3  不同改良剂处理

改良剂

Ameliorant

处理

Treatment

pH

电导率

EC/(mS/cm)

含盐量

Salinity/%

钠吸附比

SAR/(mmol1/2/L1/2)

脱硫石膏

Desulfurized gypsum

CK8.28±0.08a2.88±0.09a1.93±0.07a9.72±0.44a
G17.93±0.14b1.86±0.10b1.85±0.09ab5.18±0.10c
G27.75±0.09c1.54±0.07c1.74±0.09b7.75±0.72b
G37.84±0.12b1.05±0.07d1.39±0.03c8.80±0.66a

过磷酸钙

Calcium

superphosphate

CK8.28±0.08a2.88±0.09a1.93±0.07a9.72±0.44a
L17.67±0.10c1.16±0.07c1.44±0.06c2.53±0.10c
L28.00±0.06b1.26±0.08c1.47±0.08c2.30±0.11c
L37.87±0.07b1.54±0.06b1.74±0.09b3.21±0.77b

生物炭

Biochar

CK8.28±0.08a2.88±0.09a1.93±0.07a9.72±0.44a
T17.91±0.09b1.54±0.05b1.76±0.11b3.99±0.31c
T27.86±0.12b0.18±0.06d0.86±0.12d6.77±0.17b
T38.03±0.08b0.44±0.08c1.08±0.06c2.91±0.07d

煤渣

Coal cinder

CK8.28±0.08a2.88±0.09a1.93±0.07a9.72±0.44a
M17.43±0.12c0.55±0.10d1.25±0.10c8.34±0.22b
M27.76±0.09b1.45±0.06c1.66±0.10b2.80±0.16c
M37.84±0.08b2.40±0.06b1.89±0.09a2.27±0.21d

聚马来酸酐

Polymaleic anhydride

CK8.28±0.08a2.88±0.09a1.93±0.07a9.72±0.44a
J17.65±0.08c1.44±0.08c1.54±0.09c7.55±0.16b
J27.83±0.10b1.72±0.09b1.82±0.09ab4.18±0.20c
J37.57±0.11c1.65±0.07b1.77±0.07b2.30±0.12d
表4  不同改良剂处理对土壤pH、电导率、含盐量和钠吸附比的影响

改良剂

Ameliorant

处理

Treatment

速效钾

Available K/(mg/kg)

碱解氮

Available N/(mg/kg)

有机质

Organic matter/(g/kg)

有效磷

Available P/(mg/kg)

脱硫石膏

Desulfurized gypsum

CK381.32±2.56a37.80±3.96b9.22±0.21c6.04±0.54c
G1338.50±6.36bc43.05±1.48a13.12±1.06a8.74±0.07a
G2350.50±13.44b44.10±2.97a11.25±0.53b7.70±0.07b
G3337.00±9.90c45.50±4.95a10.87±1.06b7.75±0.13b

过磷酸钙

Calcium superphosphate

CK381.32±2.56b37.80±3.96c9.22±0.21b6.04±0.54d
L1393.00±7.07a38.85±4.45bc12.37±1.06a11.92±1.74c
L2331.00±7.07d43.05±1.48ab11.62±2.12a17.84±0.74b
L3343.00±7.07c46.90±2.97a10.95±0.11a20.39±1.00a

生物炭

Biochar

CK381.32±2.56c37.80±3.96c9.22±0.21d6.04±0.54c
T1413.50±2.12b45.50±4.95b11.25±0.53c7.65±0.54b
T2436.00±15.56a47.25±2.47b16.12±1.06b9.31±0.07a
T3442.00±2.83a63.00±7.92a18.19±0.80a10.21±1.34a

煤渣

Coal cinder

CK381.32±2.56a37.80±3.96b9.22±0.21b6.04±0.54c
M1361.50±3.54b40.25±2.47b11.06±0.27a6.47±0.74c
M2334.50±3.54c44.45±1.48a9.94±0.27b8.88±0.27b
M3324.00±15.56c40.60±1.98b11.62±1.06a9.74±0.54a

聚马来酸酐

Polymaleic anhydride

CK381.32±2.56a37.80±3.96c9.22±0.21b6.04±0.54c
J1369.00±14.14a38.15±0.49c9.94±0.27b13.76±0.20b
J2354.50±10.61b71.05±3.46b13.87±2.12a13.81±1.34b
J3334.00±7.07c78.75±2.47a14.48±0.40a15.23±0.27a
表5  不同改良剂处理对盐碱土有效养分的影响
图1  不同改良剂处理下盐碱土淋出液中Na+质量浓度变化
图2  不同改良剂处理下盐碱土淋出液中Na+积累量
图3  不同改良剂处理下盐碱土淋出液中K+质量浓度变化
图4  不同改良剂处理下盐碱土淋出液中K+积累量
图5  不同改良剂处理下盐碱土淋出液中Ca2+质量浓度变化
图6  不同改良剂处理下盐碱土淋出液中Ca2+积累量
图7  不同改良剂处理下盐碱土淋出液中Mg2+质量浓度变化
图8  不同改良剂处理下盐碱土淋出液中Mg2+积累量
参量 Parameter主成分 Principal component
1234

指标

Index

pH-0.1480.3320.5570.529
电导率 Electric conductivity0.860-0.2670.211-0.017
含盐量 Salinity0.935-0.2070.079-0.053
Ca2+0.5090.426-0.5550.386
Na0.497-0.313-0.1530.656
Mg2+0.5610.554-0.195-0.170
K0.721-0.064-0.531-0.057
钠吸附比 Sodium adsorption ratio-0.0210.764-0.182-0.453
速效钾 Available K0.701-0.2700.353-0.241
碱解氮 Available N0.1220.6670.6260.178
有机质 Organic matter0.6780.3550.531-0.167
有效磷 Available P0.0370.794-0.2790.204

初始特征值

Initial eigenvalue

特征值 Eigenvalue3.9442.6731.9241.259
百分率 Percentage/%40.24527.27619.63312.846
累计百分率 Cumulative percentage/%40.24567.52187.154100.000

荷载方差

Load variance

方差贡献率 Variance contribution rate/%32.86522.27916.03110.492
累计方差贡献率 Cumulative variance contribution rate/%32.86555.14371.17481.666
表6  各指标主成分分析

处理

Treatment

第1主成分得分

First principal

component score

第2主成分得分

Second principal

component score

第3主成分得分

Third principal

component score

第4主成分得分

Fourth principal

component score

综合得分

Synthesis score

排序

Ranking

CK-2.43-2.330.73-0.55-4.5816
G1-1.17-0.470.15-0.16-1.6512
G2-1.52-1.190.58-0.15-2.2813
G3-0.43-0.88-0.450.45-1.3010
L11.490.98-1.83-0.92-0.287
L20.722.47-2.44-0.270.475
L3-1.301.42-0.68-0.13-0.699
T1-0.41-0.740.61-0.79-1.3311
T25.07-1.700.980.194.542
T33.030.901.99-1.794.143
M11.20-2.02-0.891.20-0.528
M2-1.68-0.21-0.10-1.02-3.0114
M3-2.02-0.39-0.33-0.98-3.7215
J10.58-0.98-1.742.240.096
J2-1.122.032.922.206.031
J3-0.033.100.510.494.074
表7  各处理综合得分
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