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ZJUS-B
Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology)  2005, Vol. 6 Issue (8): 722-724    DOI: 10.1631/jzus.2005.B0722
Chemical and Environmental Engineering     
Photochemical reactions of poly(3-butoxythiophene-2,5-diyl) with chloroform
IMIT Mokhtar, YAMAMOTO Takakazu, IMIN Patigul
School of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China; Chemical Resources Laboratory, Tokyo Institute of Technology, Yokohama 226-8503, Japan
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Abstract  Photochemical reactions of poly(3-butoxythiophene-2,5-diyl) with chloroform under irradiation with light were studied. The reactions were separately carried out under air, oxygen, and nitrogen. The obtained results showed that this reaction belongs to the pseudo-first-order reaction with a rate constant kobs of 1.4×10−5 s−1 at room temperature. The presence or absence of air, oxygen, and nitrogen did not have obvious effects on the reaction rate under irradiation with light.

Key words： Poly(3-butoxythiophene-2,5-diyl)      Photochemical reaction      Kinetics     
Received: 08 May 2005     
CLC:  O644.1  
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IMIT Mokhtar
YAMAMOTO Takakazu
IMIN Patigul
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IMIT Mokhtar, YAMAMOTO Takakazu, IMIN Patigul. Photochemical reactions of poly(3-butoxythiophene-2,5-diyl) with chloroform. Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology), 2005, 6(8): 722-724.

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http://www.zjujournals.com/xueshu/zjus-b/10.1631/jzus.2005.B0722     OR     http://www.zjujournals.com/xueshu/zjus-b/Y2005/V6/I8/722

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