Please wait a minute...
ZJUS-B
Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology)  2005, Vol. 6 Issue ( 5): 8-    DOI: 10.1631/jzus.2005.B0353
    
Adsorption of ruthenium ions on activated charcoal: influence of temperature on the kinetics of the adsorption process
QADEER Riaz
Pakistan Atomic Energy Commission, Islamabad, Pakistan
Download:     PDF (0 KB)     
Export: BibTeX | EndNote (RIS)      

Abstract  Influence of temperature on ruthenium adsorption on activated charcoal from 3 mol/L HNO3 solutions was investigated in the temperature range of 288 K to 308 K. It was observed that the rise in temperature increases the adsorption of ruthenium ions on activated charcoal and follows the kinetics of first order rate law with rate constant values 0.0564-0.0640 min-1 in the temperature range of 288 K to 308 K respectively. The activation energy for the adsorption process was found to be 1.3806 kJ/mol. Various thermodynamics quantities namely ∆H, ∆S and ∆G were computed from the equilibrium constant KC values. The results indicated a positive heat of adsorption, a positive ∆S and a negative ∆G.

Key words： Atomic Energy Commission Ruthenium      Activated charcoal      Adsorption      Kinetics      Thermodynamic parameters      Nitric acid solution     
Received: 13 November 2004     
CLC:  TL375  
Service
E-mail this article
Add to my bookshelf
Add to citation manager
E-mail Alert
RSS
Articles by authors
QADEER Riaz
Cite this article:

QADEER Riaz. Adsorption of ruthenium ions on activated charcoal: influence of temperature on the kinetics of the adsorption process. Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology), 2005, 6( 5): 8-.

URL:

http://www.zjujournals.com/xueshu/zjus-b/10.1631/jzus.2005.B0353     OR     http://www.zjujournals.com/xueshu/zjus-b/Y2005/V6/I 5/8

[1] Huan-huan Pang, Meng-yi Li, Yuan Wang, Min-ke Tang, Chang-hua Ma, Jian-mei Huang. Effect of compatible herbs on the pharmacokinetics of effective components of Panax notoginseng in Fufang Xueshuantong Capsule[J]. Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology), 2017, 18(4): 343-352.
[2] Xue-hong Zhao, Jiu-kun Jiang, Yuan-qiang Lu. Evaluation of efficacy of resin hemoperfusion in patients with acute 2,4-dinitrophenol poisoning by dynamic monitoring of plasma toxin concentration[J]. Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology), 2015, 16(8): 720-726.
[3] Wen-ping Wang, Na Liu, Qian Kang, Pei-pei Du, Yi Lan, Bo-chen Zhao, Yan-yan Chen, Qing Zhang, Hui Li, Ye-wen Zhang, Qing Wu. Simultaneous determination by UPLC-MS/MS of seven bioactive compounds in rat plasma after oral administration of Ginkgo biloba tablets: application to a pharmacokinetic study[J]. Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology), 2014, 15(11): 929-939.
[4] Pan Xu, Ying Li, Shou-ying Du, Yang Lu, Jie Bai, Qing-li Guo. Comparative pharmacokinetics of borneol in cerebral ischemia-reperfusion and sham-operated rats[J]. Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology), 2014, 15(1): 84-91.
[5] Jun-jie Gao, Ye-bo Qin, Tao Zhou, Dong-dong Cao, Ping Xu, Danielle Hochstetter, Yue-fei Wang. Adsorption of methylene blue onto activated carbon produced from tea (Camellia sinensis L.) seed shells: kinetics, equilibrium, and thermodynamics studies[J]. Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology), 2013, 14(7): 650-658.
[6] Jian Liu, Jian-zhong Shentu, Li-hua Wu, Jing Dou, Qi-yang Xu, Hui-li Zhou, Guo-lan Wu, Ming-zhu Huang, Xing-jiang Hu, Jun-chun Chen. Relative bioavailability and pharmacokinetic comparison of two different enteric formulations of omeprazole[J]. Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology), 2012, 13(5): 348-355.
[7] Jing-yi Zhao, Yang Lu, Shou-ying Du, Xiao Song, Jie Bai, Yue Wang. Comparative pharmacokinetic studies of borneol in mouse plasma and brain by different administrations[J]. Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology), 2012, 13(12): 990-996.
[8] Hong Zhang, Rui-ying Li, Xia Lu, Zhen-zhen Mou, Gui-mei Lin. Docetaxel-loaded liposomes: preparation, pH sensitivity, pharmacokinetics, and tissue distribution[J]. Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology), 2012, 13(12): 981-989.
[9] Jian-ping Gao, Man Huang, Ning Li, Peng-fei Wang, Huan-lin Chen, Qiu-ping Xu. Efficacy of a novel endotoxin adsorber polyvinylidene fluoride fiber immobilized with L-serine ligand on septic pigs[J]. Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology), 2011, 12(4): 264-272.
[10] Yang Lu, Shou-ying Du, Xiao-lan Chen, Qing Wu, Xiao Song, Bing Xu, Yong-song Zhai. Enhancing effect of natural borneol on the absorption of geniposide in rat via intranasal administration[J]. Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology), 2011, 12(2): 143-148.
[11] Xue-ling He, Hai-lin Yin, Jiang Wu, Ke Zhang, Yan Liu, Tao Yuan, Hai-lin Rao, Liang Li, Guang Yang, Xue-mei Zhang. A multiple-dose pharmacokinetics of polyethylene glycol recombinant human interleukin-6 (PEG-rhIL-6) in rats[J]. Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology), 2011, 12(1): 32-39.
[12] Li-li LU, Xiu-yang LU, Nan MA. Kinetics of non-catalyzed hydrolysis of tannin in high temperature liquid water[J]. Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology), 2008, 9(5): 401-406.
[13] Ming-zhu HUANG, Jian-zhong SHENTU, Jun-chun CHEN, Jian LIU, Hui-li ZHOU. Determination of risperidone in human plasma by HPLC-MS/MS and its application to a pharmacokinetic study in Chinese volunteers[J]. Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology), 2008, 9(2): 114-120.
[14] WANG Lin-run, LIU Jian, HUANG Ming-zhu, XU Nong. Comparison of pharmacokinetics, efficacy and toxicity profile of gemcitabine using two different administration regimens in Chinese patients with non-small-cell lung cancer[J]. Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology), 2007, 8(5): 307-313.
[15] LI Ting-qiang, YANG Xiao-e, MENG Fan-hua, LU Ling-li. Zinc adsorption and desorption characteristics in root cell wall involving zinc hyperaccumulation in Sedum alfredii Hance[J]. Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology), 2007, 8(2): 111-115.