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J4  2013, Vol. 47 Issue (4): 680-686    DOI: 10.3785/j.issn.1008-973X.2013.04.018
能源工程     
太阳能光电催化还原CO2的最新研究进展
吴改, 程 军, 张梦, 周俊虎, 岑可法
浙江大学 能源清洁利用国家重点实验室,浙江 杭州 310027
Research progress of CO2 photoelectrocatalysis
WU Gai, CHENG Jun, ZHANG Meng, ZHOU Jun-hu, CEN Ke-fa
State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China
 全文: PDF 
摘要:

为了将温室气体CO2进行资源化利用,综述了太阳能转化CO2制取高值化工品和替代燃料的最新研究进展.介绍光电催化还原CO2的反应原理,指出与其他转化方式相比的优势.对于光催化与电化学的耦合反应体系、p型半导体催化剂、过渡金属催化剂、配合物催化剂如金属-四氮杂大环及吡啶型配合物、反应评价指标如反应过电位、法拉第电流效率以及电流密度等方面的国际最新研究进展进行重点评述.总结了CO2光电催化过程中的热力学和动力学难题,从中间态产物势能分布的角度对该问题的解决方案提出了建议.

关键词: 太阳能二氧化碳光电催化催化剂半导体    
Abstract:

In order to reutilize greenhouse gas CO2 as resource, the latest research progress of high-value chemicals and alternative fuels produced from CO2 using solar energy was reviewed. Reaction mechanisms and technical advantages of CO2 photoelectrocatalysis were introduced. Coupled reaction systems of photocatalytic and electrocatalytic reduction, p-type semiconductor photocatalysts, transition metal and complexes eletrocatalysts (e.g. tetraazamacrocycle and pyridine complexes), key indicators (e.g. overpotential, Faradaic efficiency and current density) were comprehensively discussed based on the latest literatures. The thermodynamic and kinetic challenges of CO2 photoelectrocatalytic reaction were summarized. It was proposed to study energy landscapes of intermediates formed in CO2 electrochemical reduction to solve these problems.

Key words: solar energy    carbon dioxide    photoelectrocatalysis    catalyst    semiconductor
出版日期: 2013-05-07
:  TK 511  
基金资助:

 国家自然科学基金资助项目(51176163);国家“863”高技术研究发展计划资助项目(2012AA050101).

通讯作者: 程军,男,教授,博导.     E-mail: juncheng@zju.edu.cn
作者简介: 吴改(1987—),男,硕士生,从事太阳能光电还原CO2制化工品研究.E-mail:21027133@zju.edu.cn
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引用本文:

吴改, 程 军, 张梦, 周俊虎, 岑可法. 太阳能光电催化还原CO2的最新研究进展[J]. J4, 2013, 47(4): 680-686.

WU Gai, CHENG Jun, ZHANG Meng, ZHOU Jun-hu, CEN Ke-fa. Research progress of CO2 photoelectrocatalysis. J4, 2013, 47(4): 680-686.

链接本文:

http://www.zjujournals.com/xueshu/eng/CN/10.3785/j.issn.1008-973X.2013.04.018        http://www.zjujournals.com/xueshu/eng/CN/Y2013/V47/I4/680

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