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浙江大学学报(工学版)
浙江大学学报(工学版)
机械与能源工程     
锂离子电池简化电化学模型：浓度分布估计
袁世斐, 吴红杰, 殷承良
上海交通大学 汽车电子控制技术国家工程实验室, 上海 200240
Simplified electrochemical model for Li-ion battery: lithium concentration estimation
YUAN Shi-fei, WU Hong-jie, YIN Cheng-liang
National Engineering Laboratory for Automotive Electronic Control Technology, Shanghai Jiao Tong University, Shanghai 200240, China
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摘要：

为了降低锂电池电化学模型的计算复杂度,提出基于修正边界条件的简化电化学模型,用于估计锂电池内部的电解液浓度分布.采用Pade逼近技术分析简化电化学模型解析解,可得到降阶的分子-分母型传递函数模型.分别采用19.38 A和193.80 A的脉冲充放电工况进行仿真对比,结果显示所提出简化模型的最大相对误差分别约为0.867%和8.670%.时域和频域模拟仿真结果表明：相比于传统电化学模型,该简化模型对电池内部电解液相的浓度分布估计具有理想的精度,同时计算复杂度得到显著优化,具备实时应用的能力.
Abstract:
A simplified electrochemical model based on modified boundary conditions was proposed to estimate the internal lithium concentration of Li-ion battery in order to reduce the computation complexity. The Pade approximation method was used to simplify the analytical solution of the electrochemical model, and the reducedorder numerator-denominator-type transfer function could be obtained. The pulse charge and discharge profiles with the magnitudes of 19.38 A and 193.80 A were employed for model verification, and the simulation results indicate that the maximum relative errors are approximately 0.867% and8.670%, respectively. Time and frequency-domain simulation results show that the proposed model has ideal accuracy for internal lithium concentration estimation when compared to traditional electrochemical model, meanwhile its computational burden has been significantly optimized, which is suitable for real-time application.
出版日期: 2017-03-01
CLC:  U 464.1  
基金资助:

国际科技合作资助项目（2010DFA72760-305）
通讯作者: 吴红杰，男，助理研究员. ORCID: 0000-0002-0169-2841.     E-mail: wuhongjie@sjtu.edu.cn
作者简介: 袁世斐（1987—），男，博士，从事电动汽车电池管理系统研究. ORCID:0000-0001-6699-646X. E-mail: shifeiyuan@qq.com
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袁世斐, 吴红杰, 殷承良. 锂离子电池简化电化学模型：浓度分布估计[J]. 浙江大学学报(工学版), 10.3785/j.issn.1008-973X.2017.03.007.

YUAN Shi-fei, WU Hong-jie, YIN Cheng-liang. Simplified electrochemical model for Li-ion battery: lithium concentration estimation. JOURNAL OF ZHEJIANG UNIVERSITY (ENGINEERING SCIENCE), 10.3785/j.issn.1008-973X.2017.03.007.

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