Based on the concentrations of SO_², NO_², CO, O_³, PM_^2.5 and PM_¹⁰ measured by Xixi monitoring station, meteorological data such as temperature, relative humidity, wind speed, visibility and rainfall, variation characteristics and correlations of various air pollutants in Hangzhou City from December 2014 to November 2016 were analyzed, and the influence of meteorological conditions on pollutants was discussed. The results showed that the concentrations of SO_² and CO reached the first grade standard of air quality during the study period. NO_² and particulate matter were severely over-standard and the average concentrations of NO_², PM_^2.5 and PM_¹⁰ were 1.21, 1.40 and 1.04 times of the second grade standards, respectively. The concentrations of all pollutants were high in winter and low in summer. However, the concentration of O_³ was high in summer and low in winter. Atmospheric oxidative O_^x remained at a relatively stable level throughout the year and was dominated by NO_² in winter and O_³ in other seasons. The concentration of PM_^2.5 was positively correlated with that of NO_² and CO, followed by SO_² and O_^x (in summer), which indicated that the local vehicle exhaust emission was an important source of atmospheric particulates. The temperature was positively correlated with O_³, and negatively correlated with other pollutants. Relative humidity, wind speed and rainfall were negatively correlated with SO_², NO_², CO, PM_^2.5 and PM_¹⁰, which showed that the pollutants were easy to diffuse under strong wind and wet deposition condition. However, CO was less affected by humidity and rainfall. This study provides a theoretical foundation for controlling atmospheric pollution in Hangzhou City.