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Application of supercritical and subcritical fluids in food processing
Maša Knez Hrnčič, Darija CÖr, Mojca Tancer Verboten, Željko Knez
Food Qual Safet, 2018, 2(2): 59-67.
https://doi.org/10.1093/fqsafe/fyy008
Using high pressure as a processing tool can overcome the legal limitations for solvent residues and restrictions on the use of conventional solvents in chemical processes. Additionally, particulate products can also be achieved by means of supercritical fluid (SCF) processing. This contribution will give a limited overview of applications of subcritical fluid and SCF and will present the energy savings compared with conventional production methods. Considering these qualities, SCFs could certainly be applied as a replacement for conventional solvents in extractive and non-extractive processes, as a nontoxic, inexpensive, non-flammable, and non-polluting solvent. Many applications, such as high pressure sterilization, jet-cutting, thin film deposition for microelectronics, and the separation of value-added products from fermentation broths in the biotechnology field, have been developed on an industrial scale to produce marketable food products.
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Residue determination of β-cyfluthrin and imidacloprid as mix formulation in/on chickpea (Cicer arietinum) pods and soil and its risk assessment
Suchi Chawla, Paresh G. Shah, Anil R.?Patel, Hemlatta K. Patel, Kiran M. Vaghela and Priti P. Solanki
Food Qual Safet, 2018, 2(2): 75-81.
https://doi.org/10.1093/fqsafe/fyy007
OBJECTIVES: A field experiment was conducted at Agricultural Research Station for irrigated crops at Thasara, Anand Agricultural University, Anand, to study the dissipation and risk assessment of β-cyfluthrin and imidacloprid as combination product in/on chickpea. MATERIALS AND METHODS: Solomon 300 OD comprising 9 per cent β-cyfluthrin and 21 per cent imidacloprid was foliar sprayed at the doses of 18 + 42g a.i. ha-1 (standard dose) and 36 + 84g a.i. ha-1 (double dose). Totally three sprays were made at an interval of 1 week starting from fruiting stage. RESULTS AND DISCUSSIONS: The residues of β-cyfluthrin estimated using gas chromatograph with electron capture detector (GC-ECD) showed an initial deposit of 0.16 and 0.27 μg g-1 in standard and double doses, respectively. The residues for corresponding doses persisted till 7th and 10th day after application and reached below determination level of 0.01μg g-1 on the 10th and 15th day, respectively. Imidacloprid was estimated using high performance liquid chromatography (HPLC) and showed initial deposits of 1.22 and 2.7 μg g-1 in standard and double doses, respectively. Its levels reached below the determination level (0.01 μg g-1) on the 15th day in green pods. Statistical analysis of dissipation kinetics showed that β-cyfluthrin followed zero-order kinetics in standard dose with half-life of 7.27 days. In double dose, the dissipation kinetics followed first-order kinetics with half-life of 9 days. Imidacloprid followed first-order kinetics in both the doses with half-life of 6.7 and 7.7 days. CONCLUSIONS: A pre-harvest interval (PHI) of 15 days is suggested. Theoretical risk assessment calculated as hazard quotient was less than 1, rendering the use of combination product as safe-provided proper PHI is followed.
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Fermentation of groundnut brittle by Lactococcus lactis produces γ-amino butyric acid and enhances nutritional quality and safety
Vibhuti Batra, Hitashi Lomash, Abhijit Ganguli
Food Qual Safet, 2018, 2(2): 83-87.
https://doi.org/10.1093/fqsafe/fyy002
Objectives The study aimed to evaluate the anti-nutrient reductions and γ-amino butyric acid (GABA) enrichments of chikki (peanut brittle), a popular of traditional snack food, using Lactococcus lactis subsp. lactis. The nutritional, storage, and sensorial analysis in order to understand the safety and functionality of chikki following fermentation were attempted. Materials and Methods Partial fermentations of chikki were carried out using overnight grown culture of L. lactis samples. The fermented chikki were further analysed for GABA and anti-nutrients. The antioxidant profile, protein, and sugar were also analysed. The storage studies were carried on up to 2 months for functional property evaluations. Results Fermentations at 37°C, pH of 5, with 1% inoculum and incubation for 24 h were optimal conditions, and resulted in the GABA concentration of 816 mg/g, respectively, and the GABA concentration did not change significantly (P > 0.05) upon storage for upto a period of 2 months. Analysis of the fermented chikki revealed a slightly higher level of phenolic, flavonoid, protein, and sugar contents as compared to those which were not subjected to fermentation. The results of sensorial analysis showed an overall general acceptability on a 5-point hedonic scale to be 8.5 ± 0.01 (before storage) and 8.03 ± 0.01 (after storage). The fermented chikki also possessed antioxidant properties and significantly (P < 0.05) low levels of phytates with complete reductions of other anti-nutrients. Conclusions Traditionally prepared/manufactured chikki lacks GABA, possesses notable levels of anti-nutrients with lower phenolics, flavonoids, as well as antioxidants. Our study suggested a simple preparation of GABA could enrich the popular ethnic snack through fermentation by L. lactis subsp. lactis. The developed snack is acceptable, economical with good shelf life, and has substantially reduced levels of anti-nutrients originating from groundnuts affording consumer safety.
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Characterizing traditional rice varieties grown in temperate regions of Italy: free and bound phenolic and lipid compounds and in vitro antioxidant properties
Pierluigi Plastina, Bartolo Gabriele and Alessia Fazio
Food Qual Safet, 2018, 2(2): 89-95.
https://doi.org/10.1093/fqsafe/fyy005
Objectives: A comparative study regarding the fatty acid profiles and antioxidant properties of the two most common varieties of rice (Carnaroli and Karnak) cultivated in Sybaris (Southern Italy) was conducted. Carnaroli variety from Pavia district (Northern Italy) was also investigated. Methods: Free and bound lipids were separately extracted. Fatty acid composition was determined by high resolution gas chromatography (HRGC). Free and bound phenolic acids were determined using high performance liquid chromatography (HPLC). The antioxidant properties were assessed using 2,2’-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging assay. Results: The total lipid content was found to be higher in both Sybaris species with respect to the Pavia variety. The lipid distribution was also significantly different. In particular, the amount of bound lipids (14.2–16.3 mg g?1) was higher than the free lipids (7.2–7.5 mg g?1), and unsaturated fatty acids (USFA) were significantly higher in the free-FA fraction than in bound-FA in both Sybaris varieties. By contrast, Carnaroli variety from Northern Italy displayed a higher content of free (5.3 mg g?1) than bound lipids (2.5 mg g?1) and a higher content of USFA in the bound-FA. The antioxidant activity of Pavia rice extract was higher than that of both Sybaris varieties. Conclusions: The two Sybaris varieties are richer in lipids than the Pavia rice, while exhibiting the same qualitative fatty acid profile with some differences in the content of individual fatty acids. The distribution of lipids (free or bound) was found to be significantly different in the Carnaroli varieties, highlighting the effects of different climatic and pedological areas.
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7 articles
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