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浙江大学学报（农业与生命科学版）
Journal of Zhejiang University (Agriculture and Life Sciences)  2006, Vol. 32 Issue (1): 31-35    DOI:
    
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Published: 27 January 2006
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. null. Journal of Zhejiang University (Agriculture and Life Sciences), 2006, 32(1): 31-35.

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https://www.zjujournals.com/agr/     OR     https://www.zjujournals.com/agr/Y2006/V32/I1/31


ZVI还原转化硝基芳烃特性及QSAR的研究

研究了零价铁(ZVI)还原转化硝基芳烃(NAC)的特性以及还原速率与分子连接性指数(MCI)的关系.结果表明:厌氧乙酸/碳酸氢钠缓冲体系(pH 5.0)中,ZVI还原转化硝基芳烃形成氨基芳烃,转化过程遵循准一级反应动力学;ZVI还原转化目标污染物活性受苯环上取代基种类、数目和位置影响,活性大小顺序为3,4-二氯硝基苯(3,4-DCN)＞邻氯硝基苯(2-CNB)＞对硝基苯胺(4-NA)＞对硝基苯酚(4-NP)＞对氯硝基苯(4-CNB)＞硝基苯(NB);目标污染物一阶分子连接性指数1Xv、四阶分子连接性指数4Xv pc和非色散力因子△x与其还原转化速率具有良好的定量的结构-活性关系(QSAR).
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[1] . null[J]. Journal of Zhejiang University (Agriculture and Life Sciences), 2006, 32(6): 658-664.
[2] . null[J]. Journal of Zhejiang University (Agriculture and Life Sciences), 2006, 32(5): 511-514.
[3] . null[J]. Journal of Zhejiang University (Agriculture and Life Sciences), 2006, 32(5): 511-519.
[4] . null[J]. Journal of Zhejiang University (Agriculture and Life Sciences), 2006, 32(5): 551-556.
[5] . null[J]. Journal of Zhejiang University (Agriculture and Life Sciences), 2006, 32(5): 473-478.
[6] . null[J]. Journal of Zhejiang University (Agriculture and Life Sciences), 2006, 32(5): 489-494.
[7] . null[J]. Journal of Zhejiang University (Agriculture and Life Sciences), 2006, 32(5): 500-504.
[8] . null[J]. Journal of Zhejiang University (Agriculture and Life Sciences), 2006, 32(5): 505-510.
[9] . null[J]. Journal of Zhejiang University (Agriculture and Life Sciences), 2006, 32(4): 444-448.
[10] . null[J]. Journal of Zhejiang University (Agriculture and Life Sciences), 2006, 32(4): 449-454.
[11] . null[J]. Journal of Zhejiang University (Agriculture and Life Sciences), 2006, 32(4): 455-459.
[12] . null[J]. Journal of Zhejiang University (Agriculture and Life Sciences), 2006, 32(4): 460-466.
[13] . null[J]. Journal of Zhejiang University (Agriculture and Life Sciences), 2006, 32(4): 467-472.
[14] . null[J]. Journal of Zhejiang University (Agriculture and Life Sciences), 2006, 32(4): 391-395.
[15] . null[J]. Journal of Zhejiang University (Agriculture and Life Sciences), 2006, 32(4): 396-400.