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IRON DETERMINATION AFTER ON-LINE SORBENT PRECONCENTRATION BY FI-FASS USING 1,10-PHENANTHROLINE AS A COMPLEXING AGENT
Akbar Ali, YE Ying-xue , XU Guang-ming, ZHANG Tao, YIN Xue-feng, JIN Xin
Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering), 2000, 1(1): 8-14.
https://doi.org/10.1631/jzus.2000.0008
1,10-Phenanthroline (phen) was tested as a complexing agent for on-line preconcentration of iron on RP-C18 material in a microcolumn with flow injection coupled with flame atomic absorption spectrometer (FI-FAAS). The on-line formed Fe(II)-phen complexes were adsorbed on the C18 sorbent material. Various parameters affecting the on-line Fe(II)-phen complex formation and its subsequent adsorption in the microcolumn as well as its elution into the nebulizer of AAS were optimized. A 2.5×10−3 mol/L phen in 2% ethanol was on-line mixed with aqueous sample solution acidified with 0.1% (v/v) HCl and allowed to flow through the microcolumn for 30 s. The adsorbed Fe(II)-phen complexes in the microcolumn were eluted with ethanol in 10 s into the nebulizer of AAS. Ascorbic acid (5×10−4 mol/L) was added to the sample solution for the reduction of Fe(III) to Fe(II). A good precision (RSD=1.1%, n=10), high enrichment factor (19) and sample throughput (90 h−1) with detection limit (3σ) of 3 μg/L were obtained. The method was applied on standard reference materials (i.e. mussel and tomato leaves,) for iron determination and yielded results agreeing well with certified values.
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POLYMERIZATION OF METHYL METHACRYLATE WITH IRON-YTTERBIUM DINUCLEAR METALLOCENE CATALYST
PAN Zhi-da, SUN Jun-quan, YANG Shi-lin
Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering), 2000, 1(1): 20-26.
https://doi.org/10.1631/jzus.2000.0020
A novel iron-ytterbium dinuclear catalyst,FcB(MeCp)Yb (MeCp) Cl (Fc: ferrocenyl, B: diethylene ether),was synthesized for the polymerization of methyl methacrylate (MMA). Synergistic effects between the ferrocenyl group and the lanthanocene part were investigated regarding their catalytic behaviors. UV, IR, GPC and NMR were used to characterize the structures of the catalyst and polymer. Kinetic study showed that polymerization is first order in monomer concentration and fractional order (0.78) in the catalyst. The bimetallic complex is a good catalyst for the polymerization of MMA, giving high molecular weight PMMA with 78% syndiotacticity.
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A KNOWLEDGE-BASED SYSTEM FOR WASTE MINIMZATION IN METAL FINISHING AND ELECTROPLATING INDUSTRIES
ZHANG Qing-yu
Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering), 2000, 1(1): 39-47.
https://doi.org/10.1631/jzus.2000.0039
This paper introduces a knowledge-based system for waste minimization in metal finishing and electroplating industries- MEPPI (minimization of environmental problems in processing industries) waste minimization techniques, such as process modification, raw materials reduction and resource recycling and recovery, and suggests its implementation in industries rather than end-of-pipe treatment.\n The data for process analysis, materials balance for each unit, and test data collection, should be inputted into MEPPI first. One can then obtain information on which unit will generate wastes, what kind waste will be produced, and the waste amount and content. Further analysis of this information can reveal if each unit is operating ideally and if the whole process is in the best state. MEPPI can indicate the possibility of waste minimization in every unit, provide all kinds of waste recovery and recycling methods for users to select from, and can reduce raw materials consumption so that the loading on the end-of-pipe treatment plant will be diminished. Realization of waste minimization will improve the economics of industries.\n MEPPI is a rich-database, friendly-interactive system integrating waste minimization audit calculation and waste minimization technique in a computer package. It can help designers to estimate the waste of a new factory and also process management or operators to minimize the release of hazardous or toxic waste into the environment.
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RESEARCH ON THE METHODS OF DETECTING AND REMOVING SLIDE VALVE FAILURE
LI Wei, LI Wei-bo, WU Gen-mao, WEI Jian-hua
Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering), 2000, 1(1): 56-60.
https://doi.org/10.1631/jzus.2000.0056
Various ways for detecting slide valve failure are discussed in the paper. Specifically, a new method for detecting slide valve sticking state is first presented. The method does not depend on any special sensor and is only based on the detection of oscillation current wave within a valve coil. Results of theoretical analysis and experimental research are given for comparison. In order to remove a slide valve sticking online, a concept and method of \"electrical hammer\" is introduced. At last, an application example of the methods is discussed. In fact, it is an electro-hydraulic turbine system with failure diagnosis, fault-tolerant and trouble removal functions.
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ESTIMATION METHOD FOR MIXED-EFFECT COEFFICIENT SEMIPARAMETRIC REGRESSION MODEL
PAN Jian-min
Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering), 2000, 1(1): 71-77.
https://doi.org/10.1631/jzus.2000.0071
Consider the mixed-effect coefficient semiparametric regression model Z=X\'α+Y\'β+g(T)+e, where X, Y and T are random vectors on Rp×Rq×[0,1], α is a p-dimensional fixed-effect parameter, β is a q-dimensional random-effect parameter (Eβ=b, Cov(β)=∑), g(.) is an unknown function on [0,1], e is a random error with mean zero and variance σ2, and (X,Y,T) and (β,e), β and e are mutually independent. We estimate α, b and g(.) by the nearest neighbor and the least square method. In this paper, we prove that estimations of α, b have asymptotic normality and obtain the best convergence rate n−1/3 for the estimation of g(.).
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MITOCHONDRIAL DYSFUNCTION AT THE EARLY STAGE OF CISPLATIN-INDUCED ACUTE RENAL FAILURE IN RATS
XIE Li-ping, C.Skrezek, H. Wand, F.Reibe
Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering), 2000, 1(1): 91-96.
https://doi.org/10.1631/jzus.2000.0091
The present study was undertaken to clarify the pathogenesis of cisplatin-induced acute renal failure at the early stage. Male Sprague-Dawley rats were given an intravenous administration of 10 mg/kg cisplatin. 0.9% saline was infused into them at a rate of 2 ml/h for 3 h, starting with a 2-ml bolus injection before cisplatin administration. 3 h following cisplatin administration, no evident morphological abnormalities were found by both light and electron microscopy; there were also no significant changes in GFR. Thirty min after cisplatin injection, urine sodium and potassium excretion increased by 56% and 260% those of the control animals, respectively. Apparent renal mitochondrial respiration dysfunction was observed in cisplatin-treated rats 3 h later; the state 4 respiration increased by 100% and state 3 respiration, respiratory control ratio and carbonyl cyanide p-trifluoromethoxyphenyl hydrazone-uncoupled respiration decreased by 46%, 74% and 47% of the controls, respectively. The present data suggest that mitochondrial dysfunction may be a very early event in cisplatin-induced acute renal failure in rats.
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18 articles
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