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Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering)  2008, Vol. 9 Issue (5): 720-726    DOI: 10.1631/jzus.A071503
Energy & Environmental Engineering     
IR study on surface chemical properties of catalytic grown carbon nanotubes and nanofibers
Li-hua TENG, Tian-di TANG
Institute of Biology and Environmental Science, Zhejiang Wanli University, Ningbo 315100, China; College of Chemistry, Northeast Normal University, Changchun 130024, China
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Abstract  In this study, the surface chemical properties of carbon nanotubes (CNTs) and carbon nanofibers (CNFs) grown by catalytic decomposition of methane on nickel and cobalt based catalysts were studied by DRIFT (Diffuse Reflectance Infrared Fourier Transform) and transmission Infrared (IR) spectroscopy. The results show that the surface exists not only carbon-hydrogen groups, but also carboxyl, ketene or quinone (carbonyl) oxygen-containing groups. These functional groups were formed in the process of the material growth, which result in large amount of chemical defect sites on the walls.

Key wordsCarbon nanotubes (CNTs)      Carbon nanofibers (CNFs)      Functional surface groups      Infrared (IR) spectroscopy     
Received: 21 September 2007      Published: 06 March 2008
CLC:  O657.3  
  O643.3  
Cite this article:

Li-hua TENG, Tian-di TANG. IR study on surface chemical properties of catalytic grown carbon nanotubes and nanofibers. Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering), 2008, 9(5): 720-726.

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http://www.zjujournals.com/xueshu/zjus-a/10.1631/jzus.A071503     OR     http://www.zjujournals.com/xueshu/zjus-a/Y2008/V9/I5/720

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