Energy & Environmental Engineering |
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IR study on surface chemical properties of catalytic grown carbon nanotubes and nanofibers |
Li-hua TENG, Tian-di TANG |
Institute of Biology and Environmental Science, Zhejiang Wanli University, Ningbo 315100, China; College of Chemistry, Northeast Normal University, Changchun 130024, China |
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Abstract In this study, the surface chemical properties of carbon nanotubes (CNTs) and carbon nanofibers (CNFs) grown by catalytic decomposition of methane on nickel and cobalt based catalysts were studied by DRIFT (Diffuse Reflectance Infrared Fourier Transform) and transmission Infrared (IR) spectroscopy. The results show that the surface exists not only carbon-hydrogen groups, but also carboxyl, ketene or quinone (carbonyl) oxygen-containing groups. These functional groups were formed in the process of the material growth, which result in large amount of chemical defect sites on the walls.
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Received: 21 September 2007
Published: 06 March 2008
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