Environmental and Energy Engineering |
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Nitrogen doping of activated carbon loading Fe2O3 and activity in carbon-nitric oxide reaction |
Wan Xian-kai , Zou Xue-quan , Shi Hui-xiang , Wang Da-hui |
Institute of Environmental Engineering, Zhejiang University, Hangzhou 310027, China |
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Abstract Nitrogen doping of activated carbon loading Fe2O3 was performed by annealing in ammonia, and the activity of the modified carbon for NO reduction was studied in the presence of oxygen. Results show that Fe2O3 enhances the amount of surface oxygen complexes and facilitates nitrogen incorporation in the carbon, especially in the form of pyridinic nitrogen. The modified carbon shows excellent activity for NO reduction in the low temperature regime (<500 °C) because of the cooperative effect of Fe2O3 and the surface nitrogen species.
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Received: 25 January 2007
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