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ZJUS-B
Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology)  2006, Vol. 7 Issue (3): 198-201    DOI: 10.1631/jzus.2006.B0198
Biochemistry & Biotechnology     
Study on the reactions of azo compounds with acyl halides mediated by Sm/TiCl4
Li Xue, Zhang Yong-Min
Department of Chemistry, Zhejiang University, Hangzhou 310028, China; State Key Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
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Abstract  Amides can be obtained in good to excellent yield by Sm/TiCl4 mediated reductive cleavage of N=N bond in azo compounds and successive acylation in one pot. It offers an alternative method for the synthesis of amides from very simple starting materials directly.

Key words： Azo compounds      Reduction      Amides      Sm/TiCl4     
Received: 24 October 2005     
CLC:  O622.6  
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Cite this article:

Li Xue, Zhang Yong-Min. Study on the reactions of azo compounds with acyl halides mediated by Sm/TiCl4. Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology), 2006, 7(3): 198-201.

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http://www.zjujournals.com/xueshu/zjus-b/10.1631/jzus.2006.B0198     OR     http://www.zjujournals.com/xueshu/zjus-b/Y2006/V7/I3/198

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