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Impact of load impedance on the performance of a thermoacoustic system employing acoustic pressure amplifier
Ke TANG, Zhong-jie HUANG, Tao JIN, Guo-bang CHEN
Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering), 2008, 9(1): 79-87.
https://doi.org/10.1631/jzus.A071340
An acoustic pressure amplifier (APA) is capable of improving the match between a thermoacoustic engine and a load by elevating pressure ratio and acoustic power output. A standing-wave thermoacoustic engine driving a resistance-and-compliance (RC) load through an APA was simulated with linear thermoacoustics to study the impact of load impedance on the performance of the thermoacoustic system. Based on the simulation results, analysis focuses on the distribution of pressure amplitude and velocity amplitude in APA with an RC load of diverse acoustic resistances and compliance impedances. Variation of operating parameters, including pressure ratio, acoustic power, hot end temperature of stack, etc., versus impedance of the RC load is presented and analyzed according to the abovementioned distribution. A verifying experiment has been performed, which indicates that the simulation can roughly predict the system operation in the fundamental-frequency mode.
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Bubble counter based on photoelectric technique for leakage detection of cryogenic valves
Tao JIN, Bin XU, Ke TANG, Jian-ping HONG
Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering), 2008, 9(1): 88-92.
https://doi.org/10.1631/jzus.A071430
In order to overcome the inconvenience of manual bubble counting, a bubble counter based on photoelectric technique aiming for automatically detecting and measuring minute gas leakage of cryogenic valves is proposed. Experiments have been conducted on a self-built apparatus, testing the performance with different gas inlet strategies (bottom gas-inlet strategy and side gas-inlet strategy) and the influence of gas pipe length (0, 1, 2, 4, 6, 8, 10 m) and leakage rate (around 10, 20, 30, 40 bubbles/min) on first bubble time and bubble rate. A buffer of 110 cm3 is inserted between leakage source and gas pipe to simulate the downstream cavum adjacent to the valve clack. Based on analyzing the experimental data, experiential parameters have also been summarized to guide leakage detection and measurement for engineering applications. A practical system has already been successfully applied in a cryogenic testing apparatus for cryogenic valves.
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Computational fluid dynamic simulation of an inter-phasing pulse tube cooler
Xiao-bin ZHANG, Zhi-hua GAN, Li-min QIU, Hua-xiang LIU
Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering), 2008, 9(1): 93-98.
https://doi.org/10.1631/jzus.A071259
An inter-phasing pulse tube cooler (IPPTC) consists of two pulse tube units, which are connected to each other at hot ends of the pulse tubes through a needle valve. This paper presents the computational fluid dynamic (CFD) results of an IPPTC using a 2D axis-symmetrical model. General results such as the phase difference between pressure and velocity at cold end and hot end, the temperature profiles along the wall, the available lowest temperature as well as its oscillations and the coefficient of performance (COP) for IPPTC are presented. The formation of DC flow and its effects on the performance of the cooler are investigated and analyzed in detail. Turbulence, which is partially responsible for the poor overall performance of a single orifice pulse tube cooler (OPTC), is found to be much reduced in IPPTC and its performance is improved significantly compared with the single OPTC.
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Parameter optimization model in electrical discharge machining process
Qing GAO, Qin-he ZHANG, Shu-peng SU, Jian-hua ZHANG
Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering), 2008, 9(1): 104-108.
https://doi.org/10.1631/jzus.A071242
Electrical discharge machining (EDM) process, at present is still an experience process, wherein selected parameters are often far from the optimum, and at the same time selecting optimization parameters is costly and time consuming. In this paper, artificial neural network (ANN) and genetic algorithm (GA) are used together to establish the parameter optimization model. An ANN model which adapts Levenberg-Marquardt algorithm has been set up to represent the relationship between material removal rate (MRR) and input parameters, and GA is used to optimize parameters, so that optimization results are obtained. The model is shown to be effective, and MRR is improved using optimized machining parameters.
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Effect of nitrogen doping on the reduction of nitric oxide with activated carbon in the presence of oxygen
Xian-kai WAN, Hui-xiang SHI, Xue-quan ZOU, Peng GE, Da-hui WANG
Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering), 2008, 9(1): 113-117.
https://doi.org/10.1631/jzus.A073019
Nitrogen doping of activated carbon (AC) was performed by annealing both in ammonia and nitric oxide, and the activities of the modified carbons for NO reduction were studied in the presence of oxygen. Results show that nitrogen atoms were incorporated into the carbons, mostly in the form of pyridinic nitrogen or pyridonic nitrogen. The effect of nitrogen doping on the activities of the carbons can be ignored when oxygen is absent, but the doped carbons show desirable activities in the low temperature regime (≤500 °C) when oxygen is present. The role of the surface nitrogen species is suggested to promote the formation of NO2 in the presence of oxygen, and NO2 can facilitate decomposition of the surface oxygen species in the low temperature regime.
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Kinetics of 2,4-dichlorophenol dechlorination by Pd-Fe bimetallic nanoparticles in the presence of humic acid
Zhen ZHANG, Jing-jing WO, Naman CISSOKO, Xin-hua XU
Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering), 2008, 9(1): 118-124.
https://doi.org/10.1631/jzus.A071313
The remediation of groundwater which contains chlorinated organic compounds (COCs) by nanoscale bimetallic catalysts has received increasing interest in recent years. This report presents the dechlorination of 2,4-dichlorophenol (2,4-DCP) by Pd-Fe bimetallic nanoparticles in the presence of humic acid (HA) to investigate the feasibility of using Pd-Fe for the in situ remediation of contaminated groundwater. Our experimental results indicated that HA had an adverse effect on the dechlorination of 2,4-DCP by Pd-Fe nanoparticles. The rate constant k values of 2,4-DCP dechlorination were 0.017, 0.013, 0.009, 0.006 and 0.004 min−1 for HA concentrations of 0, 5, 10, 15 and 20 mg/L, respectively. The relationship between HA dosage and k values can be described as a linear model.
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Mechanisms of phosphate removal from aqueous solution by blast furnace slag and steel furnace slag
Sheng-gao LU, Shi-qiang BAI, Hong-dan SHAN
Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering), 2008, 9(1): 125-132.
https://doi.org/10.1631/jzus.A071272
We report the adsorption of phosphate and discuss the mechanisms of phosphate removal from aqueous solution by burst furnace slag (BFS) and steel furnace slag (SFS). The results show that the adsorption of phosphate on the slag was rapid and the majority of adsorption was completed in 5~10 min. The adsorption capacity of phosphate by the slag was reduced dramatically by acid treatment. The relative contribution of adsorption to the total removal of phosphate was 26%~28%. Phosphate adsorption on BFS and SFS follows the Freundlich isotherm, with the related constants of k 6.372 and 1/n 1.739 for BFS, and of k 1.705 and 1/n 1.718 for SFS. The pH and Ca2+ concentration were decreased with the addition of phosphate, suggesting the formation of calcium phosphate precipitation. At pH 2.93 and 6.93, phosphate was desorbed by about 36%~43% and 9%~11%, respectively. These results indicate that the P adsorption on the slag is not completely reversible and that the bond between the slag particles and adsorbed phosphate is strong. The X-ray diffraction (XRD) patterns of BFS and SFS before and after phosphate adsorption verify the formation of phosphate salts (CaHPO4·2H2O) after adsorption process. We conclude that the removal of phosphate by BFS and SFS is related to the formation of phosphate calcium precipitation and the adsorption on hydroxylated oxides. The results show that BFS and SFS removed phosphate nearly 100%, indicating they are promising adsorbents for the phosphate removal in wastewater treatment and pollution control.
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Hole transport and phonon scattering in epitaxial PbSe films
Jian-xiao SI, Hui-zhen WU, Tian-ning XU, Chun-fang CAO
Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering), 2008, 9(1): 137-142.
https://doi.org/10.1631/jzus.A071350
The combined characterizations of mobility and phonon scattering spectra allow us to probe hole transport process in epitaxial PbSe crystalline films grown by molecular beam epitaxy (MBE). The measurements of Hall effect show p-type conductivity of PbSe epitaxial films. At 295 K, the PbSe samples display hole concentrations of (5~8)×1017 cm–3 with mobilities of about 300 cm2/(V·s), and at 77 K the hole mobility is as high as 3×103 cm2/(V·s). Five scattering mechanisms limiting hole mobilities are theoretically analyzed. The calculations and Raman scattering measurements show that, in the temperatures between 200 and 295 K, the scattering of polar optical phonon modes dominates the impact on the observed hole mobility in the epitaxial PbSe films. Raman spectra characterization observed strong optical phonon scatterings at high temperature in the PbSe epitaxial films, which is consistent with the result of the measured hole mobility.
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Hydrothermal synthesis and characterization of two novel inorganic-organic hybrid materials
Zeng-he LI, Hai-dan BAI
Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering), 2008, 9(1): 143-148.
https://doi.org/10.1631/jzus.A071180
By using different organic ligands, two 3D inorganic-organic hybrid compounds Co(C4H4N2)(VO3)2 1 and Co(C12H12N2)(VO3)2 2 were synthesized by hydrothermal reaction and characterized by X-ray crystallography. Crystal data: 1. crystal system orthorhombic, space group Pnna, a=10.188(2) Å, b=11.497(2) Å, c=7.3975(15) Å, V=866.5(3) Å3, Z=4, Dcalcd=2.705 g/cm3; 2. crystal system triclinic, space group P1– (No. 2), a=8.3190(17) Å, b=8.4764(17) Å, c=11.183(2) Å, α=95.48(3)°, β=92.03(3)°, γ=107.24(3)°, V=748.0(3) Å3, Z=2, Dcalcd=1.958 g/cm3. The framework of compound 1 contains both {Co(C4H4N2)} and infinite metavanadate chains. Crystal structure of compound 2 is constructed with inorganic {CoV2O6} layers across-linked by organic 1,2-bis(4-pyridyl) ethane ligands. The two compounds are thermally stable to approximately 410 °C and 350 °C, respectively. Their optical band gaps are determined to be 2.13 eV and 2.12 eV by UV-VIS-NIR diffuse reflectance spectra, which revealed their nature of semiconductor and optical absorption features.
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21 articles
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