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Syntheses and characterizations of alloyed CoxNi1−xO nanocrystals |
Xin Wang, Zhi-zhen Ye, Yi-zheng Jin |
State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China; Center for Chemistry of High-Performance and Novel Materials, State Key Laboratory of Silicon Materials, Department of Chemistry, Zhejiang University, Hangzhou 310027, China |
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Abstract Alloying is an effective way to manipulate the composition and physico-chemical properties of functional materials. We demonstrated the syntheses of alloyed CoxNi1−xO nanocrystals using a nonaqueous approach, with x continuously tuned from 0 to 1 by varying the molar ratios of the cobalt precursor in the reagents. The morphological, structural, and compositional properties of the alloyed CoxNi1−xO nanocrystals were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), inductively coupled plasma atomic emission spectroscopy (ICP-AES), and energy dispersive X-ray spectroscopy (EDS). The results showed that the cobalt and nickel atoms were homogeneously distributed in the alloyed nanocrystals. The as-prepared CoxNi1−xO nanocrystals can be applied as the hole-transporting layers in polymer light emitting diodes (PLEDs). Our study provides a good example for the syntheses of alloyed oxide nanocrystals with continuously tunable composition.
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Received: 26 May 2016
Published: 05 April 2017
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