Chemical & Environmental Engineering |
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Water quality improvement of a lagoon containing mixed chemical industrial wastewater by micro-electrolysis-contact oxidization |
Ya-fei Zhou, Mao Liu, Qiong Wu |
College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China; The Eleventh Design & Research Institute of IT, Co., Ltd, Dalian Office, Dalian 116600, China |
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Abstract A lagoon in the New Binhai District, a high-speed developing area, Tianjin, China, has long been receiving the mixed chemical industrial wastewater from a chemical industrial park. This lagoon contained complex hazardous substances such as heavy metals and accumulative pollutants which stayed over time with a poor biodegradability. According to the characteristics of wastewater in the lagoon, the micro-electrolysis process was applied to improve the biodegradability before the bioprocess treatment. By the orthogonal experimental study of main factors influencing the efficiency of the treatment method, the best control parameters were obtained, including pH=2.0, a volume ratio of Fe and reaction wastewater of 0.03750, a volume ratio of Fe and the granular activated carbon (GAC) of 2.0, a mixing speed of 200 r/min, and a hydraulic retention time (HRT) of 1.5 h. In the meantime, the removal rate of chemical oxygen demand (COD) was up to 64.6%, and NH4+–N and Pb in the influent were partly removed. After the micro-electrolysis process, the ratio of biochemical oxygen demand (BOD) to COD (B/C ratio) was greater than 0.6, thus providing a favorable basis for bioprocess treatment.
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Received: 30 June 2010
Published: 09 May 2011
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