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Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering)  2010, Vol. 11 Issue (8): 613-618    DOI: 10.1631/jzus.A1000043
Chemical and Environmental Engineering     
Hydrothermal production of formic and acetic acids from syringol
Lu-ting Pan, Zheng Shen, Lei Wu, Ya-lei Zhang, Xue-fei Zhou, Fang-ming Jin
MOE, Key Laboratory of Yangtze River Water Environment, State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China
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Abstract  The production of formic and acetic acids (or salts) by hydrothermal oxidation of syringol, a model compound for lignin, was investigated using a batch reactor. Results show that the highest yields of formic and acetic acids were, respectively, 59.6% and 11.3% at the reaction condition of 0.5 mol/L NaOH, 120% H2O2 supply and 280 掳C. These results will inform studies aiming to develop more environmental friendly lignin conversion processes by obtaining products beyond a CO2 end product.

Key wordsLignin      Syringol      Formic acid      Acetic acid      Clarification')" href="#">Hydrothermal process

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Received: 27 January 2010      Published: 02 August 2010
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Ya-lei Zhang
Lu-ting Pan
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Lei Wu
Xue-fei Zhou
Fang-ming Jin
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Lu-ting Pan, Zheng Shen, Lei Wu, Ya-lei Zhang, Xue-fei Zhou, Fang-ming Jin. Hydrothermal production of formic and acetic acids from syringol. Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering), 2010, 11(8): 613-618.

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http://www.zjujournals.com/xueshu/zjus-a/10.1631/jzus.A1000043     OR     http://www.zjujournals.com/xueshu/zjus-a/Y2010/V11/I8/613

[1] Zheng SHEN, Fang-ming JIN, Ya-lei ZHANG, Bing WU, Jiang-lin CAO. Hydrogen transfer reduction of ketones using formic acid as a hydrogen donor under hydrothermal conditions[J]. Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering), 2009, 10(11): 1631-1635.