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ZJUS-A
Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering)  2006, Vol. 7 Issue (11): 19-    DOI: 10.1631/jzus.2006.A1928
    
Solvent effects on hydrogen bonding between primary alcohols and esters
DHARMALINGAM K., RAMACHANDRAN K., SIVAGURUNATHAN P.
Department of Physics, Annamalai University, Annamalai Nagar, 608002, Tamilnadu, India
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Abstract  The interaction by hydrogen bond formation of some primary alcohols (1-heptanol, 1-octanol and 1-decanol) with esters (methyl methacrylate, ethyl methacrylate and butyl methacrylate) was investigated in non-polar solvents viz., n-heptane, CCl4 and benzene by means of FTIR spectroscopy. Formation constants and free energy changes of complex formation were determined. The dependence of the equilibrium constants and free energy changes of complex formation on the alkyl chain length of both the alcohols and esters are discussed. The solvent effect on the hydrogen bond formation is discussed in terms of specific interaction between the solute and solvent.

Key words： FTIR spectroscopy      Primary alcohols      Esters      Hydrogen bonding      Solvent effect     
Received: 20 February 2006     
CLC:  X703  
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DHARMALINGAM K.
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Cite this article:

DHARMALINGAM K., RAMACHANDRAN K., SIVAGURUNATHAN P.. Solvent effects on hydrogen bonding between primary alcohols and esters. Journal of Zhejiang University-SCIENCE A (Applied Physics & Engineering), 2006, 7(11): 19-.

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http://www.zjujournals.com/xueshu/zjus-a/10.1631/jzus.2006.A1928     OR     http://www.zjujournals.com/xueshu/zjus-a/Y2006/V7/I11/19

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