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浙江大学学报（理学版）
浙江大学学报（理学版）  2016, Vol. 43 Issue (3): 321-324    DOI: 10.3785/j.issn.1008-9497.2016.03.013
化学     
植酸修饰聚乙烯醇纤维膜负载钯催化剂的制备及其性能研究
钟少锋1, 区琼荣2
1. 浙江工业职业技术学院 纺织工程分院, 浙江 绍兴 312000;
2. 复旦大学 光源与照明系, 上海 200433
Phytic acid modified poly(vinyl alcohol) fiber mats supported palladium catalyst and its catalytic performance
ZHONG Shaofeng1, OU Qiongrong2
1. Department of Textile, Zhejiang Industry Polytechnic College, Shaoxing 312000, Zhejiang Province, China;
2. Light Sources and Illuminating Engineering College, Fudan University, Shanghai 200433, China
 全文: PDF(442 KB)  
摘要： 利用静电纺丝和交联技术,制备了植酸(PA)修饰聚乙烯醇(PVA)纤维膜负载钯催化剂.利用扫描电子显微镜(SEM)表征了纤维膜的微观结构;采用扫描电子显微镜-能谱仪(SEM-EDS)分析了Pd催化中心在纤维膜上的分布;采用红外光谱研究了纤维膜的化学结构.Mizoroki-Heck偶联反应结果显示,植酸的引入可以提高纤维膜催化剂的催化活性;该催化剂对不同结构的碘代芳烃和丙烯酸酯都表现出良好的催化性能;而且该催化剂至少可以重复使用4次其活性基本保持不变.
关键词： 钯催化剂;  负载催化剂;  Mizoroki-Heck反应;  静电纺丝;  植酸    
Abstract: Phytic acid modified poly(vinyl alcohol) fiber mat is prepared by electro spinning and used as the supporting materials of palladium catalyst. The fiber morphologies are recorded by scanning electron microscopy (SEM) and the dispersion of palladium particles is analyzed by SEM- Energy Dispersive Spectrometer (SEM-EDS). FT-IR spectra are used to characterize the chemical structure of the fiber mat. The catalytic performance of this novel catalyst is evaluated by Mizoroki-Heck reactions. The results show that this catalyst is very efficient for the Mizoroki-Heck reaction of aromatic iodides with yields being over 85%. Moreover, the catalyst could be used four times with only little loss of catalytic activity.
Key words: palladium catalyst    supported catalyst    Mizoroki-Heck reaction    electro spinning    phytic acid
收稿日期: 2015-09-01 出版日期: 2016-03-01
CLC:  O643.37  
基金资助: 校级高层次平台资助计划项目(111000210920715513);浙江省教育厅高职高专院校省级专业带头人领军项目(lj2013131).
作者简介: 钟少锋(1976-),ORCID:http://orcid.org/0000-0002-0590-5293,男,博士,副教授,主要从事功能高分子制备和改性研究,E-mail:sfzhong76@163.com.
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引用本文:

钟少锋, 区琼荣. 植酸修饰聚乙烯醇纤维膜负载钯催化剂的制备及其性能研究[J]. 浙江大学学报（理学版）, 2016, 43(3): 321-324.

ZHONG Shaofeng, OU Qiongrong. Phytic acid modified poly(vinyl alcohol) fiber mats supported palladium catalyst and its catalytic performance. Journal of ZheJIang University(Science Edition), 2016, 43(3): 321-324.

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https://www.zjujournals.com/sci/CN/10.3785/j.issn.1008-9497.2016.03.013    或    https://www.zjujournals.com/sci/CN/Y2016/V43/I3/321

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