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浙江大学学报（理学版）
浙江大学学报（理学版）
化学     
Fe-Al-络合催化马来酸酐与环氧氯丙烷 共聚合特征研究
(宁波大学化学系 , 浙江 宁波 315020)
Alternating copolymerization of maleic anhydride and epichlorohydrin
( Department of Chemistry, Ningbo University, Ningbao 310035,China)
 全文: PDF(133 KB)  
摘要： 本文研究了马来酸酐与环氧氯丙烷交替共聚 ,研究了 Fe(acac) 3-Al(i-Bu) -α ,α  联吡啶络合物 (acac= 乙酰丙酮 )催化马来酸酐 (M A)和环氧氯丙烷交替共聚的特征 . 并用红外光谱、核磁共振谱研究 了共聚物的结构 .
关键词： 马来酸酐;  环氧氯丙烷 ;  Fe-Al-α;  α  联吡啶络合催化剂;  交替共聚     
Abstract: The characteristics and structure of alternating copolym erization of maleic anhydride with epichlorohydrin by Fe-Al-α ,α  -dipyridyl w ere presented and discussed. The copolym er was characterized and discussed. The copolymer was characterized by IR and 1 H-NM R. The copolymer is a product of high alternation. Meleic anhydride is 48. 6% in the copolymer. The coploymerization can be realized in the solvents such as aromatic hydrocarbon and alkane. The yieldis higher in aromatic hydrocarbon than the others. The suitable Al/Fe molar ratio is 2～ 6. The suitable Fe /α ,α  -dipyridyl molar ratio is 1.
Key words: maleic anhydride    epichlorohydrin    Fe-Al-α    α  -dipyridyl catalyst    alternating copolym erization
出版日期: 2010-06-03
CLC:  O621. 25  
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黄士力
房江华
徐　晖
章哲彦

引用本文:

黄士力,房江华,徐　晖,章哲彦 . Fe-Al-络合催化马来酸酐与环氧氯丙烷 共聚合特征研究 [J]. 浙江大学学报（理学版）, .

HU ANG Shili, FANG J iang-hua, XU Hui, ZHANG Ze-yan . Alternating copolymerization of maleic anhydride and epichlorohydrin. Journal of Zhejiang University (Science Edition), .

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https://www.zjujournals.com/sci/CN/    或    https://www.zjujournals.com/sci/CN/Y2000/V27/I2/175

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