Studies on the Aromatic Rings Stacking Interaction of the Ternary Mixed Ligand ComplexesN .Investigation on Extraction and Synthesis Characterizationof Mixed Ligand Complexes in the Znz+一phen-PCA一System.
(Department of Chemistry of Hangzhou University,Hangzhou 310028)
Abstract： "hhe ,tacking interactions of aromatic rings in the Zn`+-phen-PCA- System (phen=1，10 phenan-tl}ruline.PcA二phenylcarboxylic acid)have been studied by extraction and synthesis methods. The con-rent of the stacked isomers is [Zn(phen>}(PLA)(H:O)}]NO,，(n=1,2) and the st佑changes in the fol-lowing order:[Zn(phen):(Bz)( HBO)〕+<[Zn (phen ) } (PAc ) (HBO )〕十<[Zn (phen )} (PPr ) (HBO ) ]+>[Zn(phen):(PBu)(H,o)]+.These solid complexes were characterized by elemental analyses ,molar con-ductance，IR and iJV spectra .TG and DTA and 'HNMR techniques.
林秋月;龚枉秋. 三元混配合物中的芳环堆积作用研究‘N . Zn2十一Phen-PCA体系的萃取研究和混配合物的合成及表征[J]. 浙江大学学报（理学版）, 1997, 24(3): 234-238.
Lin Qiuyue Gong Yuqiu. Studies on the Aromatic Rings Stacking Interaction of the Ternary Mixed Ligand ComplexesN .Investigation on Extraction and Synthesis Characterizationof Mixed Ligand Complexes in the Znz+一phen-PCA一System.. Journal of ZheJIang University(Science Edition), 1997, 24(3): 234-238.
