Please wait a minute...
浙江大学学报（理学版）
浙江大学学报（理学版）  2017, Vol. 44 Issue (5): 568-575    DOI: 10.3785/j.issn.1008-9497.2017.05.012
环境科学     
造纸污泥活性炭在催化臭氧氧化降解橙黄Ⅱ中的应用研究
史宇滨1, 陈子文2, 鲍玥1, 邹骏华1, 万先凯1, 史惠祥1
1. 浙江大学 环境工程研究所, 浙江 杭州 310058;
2. 深圳能源资源综合开发有限公司, 广东 深圳 518031
Application research on paper mill sludge-derived activated carbon in catalytic ozonation degradation of orange Ⅱ
SHI Yubin1, CHEN Ziwen2, BAO Yue1, ZOU Junhua1, WAN Xiankai1, SHI Huixiang1
1. Institute of Environmental Engineering, Zhejiang University, Hangzhou 310058, China;
2. Shenzhen Energy Resource Comprehensive Development Co., Ltd, Shenzhen 518031, Guangdong Province, China
 全文: PDF(1341 KB)   HTML  
摘要： 采用化学活化法将造纸污泥制备成活性炭，运用SEM、BET、EDS、FT-IR等常规表征技术分析其理化性质，再将制备的污泥活性炭作为催化剂，应用于催化臭氧氧化降解橙黄Ⅱ模拟染料废水，并考察不同因素对橙黄Ⅱ降解效果的影响，探究污泥活性炭催化臭氧氧化橙黄Ⅱ的反应机理.结果表明：（1）造纸污泥活性炭的理想制备条件为：原污泥与氯化锌质量比为1：2，活化时间为12 h，炭化温度为600℃，炭化时间为60 min.（2）在污泥活性炭催化臭氧体系中，污泥活性炭投加量和臭氧流量的增加有利于橙黄Ⅱ去除率的提高，但随着溶液初始pH值的增大，橙黄Ⅱ去除率降低.
关键词： 染料废水;  催化臭氧氧化;  造纸污泥;  活性炭;  橙黄    
Abstract: The activated sludge activated carbon (SAC) prepared by chemical activation method was characterized by several methods including SEM, BET, EDS, FT-IR. The prepared SAC performed as catalyst in ozonation degradation of orange Ⅱ, and the removal efficiency of orange Ⅱ under different reaction conditions was investigated. In addition, the reaction mechanism of degrading orange Ⅱ through catalytic ozonation with SAC was studied. The results indicated that the optimal preparation conditions are as follows:the mass ratio between sludge and activation reagent is 1:2, activation time is 12 h, buring temperature is 600℃, burning time is 60 min. Moreover, the increase of SAC dosage and ozone inlet fluxes was beneficial to the removal efficiency of orange Ⅱ. However, orange Ⅱ removal rate decreased when the initial pH value of the solution increased.
Key words: dye wastewater    catalytic ozonation    paper mill sludge    activated carbon    orange
收稿日期: 2016-09-26 出版日期: 2017-05-01
CLC:  X703  
基金资助: 浙江省重大科技专项计划项目（2014C03002）.
通讯作者: 史惠祥,ORCID:http://orcid.org/0000-0002-5704-4229,E-mail:huixiang_shi@163.com.     E-mail: huixiang_shi@163.com
作者简介: 史宇滨(1991-),ORCID:http://orcid.org/0000-0002-8434-3785,男,硕士,主要从事水污染控制技术研究.
服务　　
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章　　
史宇滨
陈子文
鲍玥
邹骏华
万先凯
史惠祥

引用本文:

史宇滨, 陈子文, 鲍玥, 邹骏华, 万先凯, 史惠祥. 造纸污泥活性炭在催化臭氧氧化降解橙黄Ⅱ中的应用研究[J]. 浙江大学学报（理学版）, 2017, 44(5): 568-575.

SHI Yubin, CHEN Ziwen, BAO Yue, ZOU Junhua, WAN Xiankai, SHI Huixiang. Application research on paper mill sludge-derived activated carbon in catalytic ozonation degradation of orange Ⅱ. Journal of ZheJIang University(Science Edition), 2017, 44(5): 568-575.

链接本文:

https://www.zjujournals.com/sci/CN/10.3785/j.issn.1008-9497.2017.05.012    或    https://www.zjujournals.com/sci/CN/Y2017/V44/I5/568

[1] 任南琪,周显娇,郭婉茜,等.染料废水处理技术研究进展[J].化工学报,2013,64(1):11-17. REN N Q, ZHOU X J, GUO W Q, et al. A review on treatment methods of dye wastewater[J]. CIESC Journal,2013,64(1):11-17.
[2] 梁晓霞.非均相催化-臭氧氧化处理偶氮染料废水的研究[D].天津:天津科技大学,2014. LIANG X X. Study on Treatment of Azo Dye Wastewater With Heterogeneous Catalytic Ozonation[D]. Tianjin:Tianjin University of Science & Technology,2014.
[3] 李海健,李文兵,万栋,等.CTAB-膨润土的制备、表征及对橙黄Ⅱ的吸附研究[J].水处理技术,2014,40(9):74-77. LI H J, LI W B, WAN D, et al. Preparation and characterization of CTAB-Bentonite and its adsorption on Orange Ⅱ[J]. Technology of Water Treatment,2014,40(9):74-77.
[4] 马军,刘正乾,虞启义,等.臭氧多相催化氧化除污染技术研究动态[J].黑龙江大学自然科学学报,2009,26(1):1-15. MA J, LIU Z Q, YU Q Y, et al. A review on pollutant removal by heterogeneous catalytic oxidation with ozone[J]. Journal of Nature Science of Heilongjiang University,2009,26(1):1-15.
[5] 李璐.污泥基活性炭催化臭氧氧化去除水中对氯苯甲酸效能与机理研究[D].北京:北京林业大学,2014. LI L. The Effect and Mechanism Study on the Removal of p-Chlorobenzoic Acid by Catalytic Ozonation with Sludge-Corncob Activated Carbon[D]. Beijing:Beijing Forestry University,2014.
[6] 胡立鹃,吴峰,彭善枝,等.生物质活性炭的制备及应用进展[J].化学通报,2016,79(3):205-212. HU L J, WU F, PENG S Z, et al. Progress in preparation and utilization of biomass-based activated carbons[J]. Chemistry,2016,79(3):205-212.
[7] CALISTO V, FERREIRA C I A, SANTOS S M, et al. Production of adsorbents by pyrolysis of paper mill sludge and application on the removal of citalopram from water[J]. Bioresource Technology,2014,166:335-344.
[8] 丛高鹏,施英乔,丁来保,等.造纸污泥生物质资源化利用[J].生物质化学工程,2011,45(5):37-45. CONG G P, SHI Y Q, DING L B, et al. Biomass resource utilization of paper mill sludge[J]. Biomass Chemical Engineering,2011,45(5):37-45.
[9] IKHLAQ A, BROWN D R, KASPRZYK-HORDERN B. Mechanisms of catalytic ozonation:An investigation into superoxide ion radical and hydrogen peroxide formation during catalytic ozonation on alumina and zeolite in water[J]. Applied Catalysis B:Environmental,2013,129:437-449.
[10] WEN G, PAN Z H, MA J, et al. Reuse of sewage sludge as a catalyst in ozonation-efficiency for the removal of oxalic acid and the control of bromate formation[J]. Journal of Hazardous Materials,2012,239/240:381-388.
[11] 余兰兰,钟秦,冯兰兰.剩余污泥制备活性炭吸附剂及其应用研究[J].安全与环境学报,2005(4):39-42. YU L L, ZHONG Q, FENG L L. Excess sludge activated carbon adsorbent preparation and its application research[J]. Journal of Safety and Environment,2005(4):39-42.
[12] SMITH K M, FOWLER G D, PULLKET S, et al. Sewage sludge-based adsorbents:A review of their production, properties and use in water treatment applications[J]. Water Research,2009,43(10):2569-2594.
[13] ROZADA F, OTERO M, MORÁN A, et al. Adsorption of heavy metals onto sewage sludge-derived materials[J]. Bioresource Technology,2008,99(14):32-38.
[14] LEBIGUE C J, ANDRIANTSIFERANA C, KROU N G, et al. Application of sludge-based carbonaceous materials in a hybrid water treatment process based on adsorption and catalytic wet air oxidation[J]. Journal of Environmental Management,2010,91(12):32-39.
[15] CALISTO V, FERREIRA C I A, SANTOS S M, et al. Production of adsorbents by pyrolysis of paper mill sludge and application on the removal of citalopram from water[J]. Bioresource Technology,2014,166:335-344.
[16] ZHAO L, SUN Z Z, MA J, et al. Enhancement mechanism of heterogeneous catalytic ozonation by cordierite-supported copper for the degradation of nitrobenzene in aqueous solution[J]. Environmental Science & Technology,2009,43(6):2047-2053.
[17] 古励.吸附-催化臭氧氧化协同降解液相有机污染物的研究[D].杭州:浙江大学,2009.GU L. Study on Synergistic Degradation of Aqueous Organic Contaminants by Adsorption-Catalytic Ozonation System[D]. Hangzhou:Zhejiang University,2009.
[18] LÁSZLÓ K, TOMBÁCZ E, NOVÁK C. pH-dependent adsorption and desorption of phenol and aniline on basic activated carbon[J]. Colloids & Surfaces a Physicochemical & Engineering Aspects,2007,3
[1] 贺斯佳,张硕,孙昊,郭庆龄,翁琦辉,杨岳平. 活性炭吸附饮用水中三卤甲烷的实验研究[J]. 浙江大学学报（理学版）, 2022, 49(4): 489-497.
[2] 战晓慧, 周高燕, 周尚平, 章静, 方荣业, 史惠祥. 复苏促进因子增效PACT处理印染废水[J]. 浙江大学学报（理学版）, 2021, 48(2): 241-248.
[3] 张平, 杨岳平, 赵丹, 武云霞, 陈莎莎. 饮用水中三氯甲烷与其他氯消毒副产物在活性炭上的吸附竞争研究[J]. 浙江大学学报（理学版）, 2020, 47(1): 107-114.
[4] 方荣业, 史宇滨, 蒋婷, 李威, 史惠祥. 基于BP神经网络的城镇污水厂活性炭自动投加系统研究[J]. 浙江大学学报（理学版）, 2018, 45(4): 468-475.
[5] 荆王松, 王长智, 梅荣武, 史惠祥, 徐峰. 改性磁铁矿/H2O2非均相类Fenton体系催化降解橙黄Ⅱ的研究[J]. 浙江大学学报（理学版）, 2018, 45(4): 461-467.