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浙江大学学报(工学版)
浙江大学学报(工学版)  2017, Vol. 51 Issue (12): 2373-2382    DOI: 10.3785/j.issn.1008-973X.2017.12.009
土木与交通工程     
蒙脱石电渗微观机理试验研究
郭康仕1, 庄艳峰1, 段伟2
1. 武汉大学 土木建筑工程学院, 湖北 武汉 430072;
2. 武汉建工集团股份有限公司, 湖北 武汉 430023
Experimental study on micro-mechanism of electro-osmosis using montmorillonite
GUO Kang-shi1, ZHUANG Yan-feng1, DUAN Wei2
1. School of Civil Engineering, Wuhan University, Wuhan 430072, China;
2. Wuhan Construction Engineering Group Co. Ltd, Wuhan 430023, China
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摘要：

为了在微观上探究电渗的作用机理，以单一矿物成分的蒙脱石为电渗对象，采用自制金属电极和EKG电极，设计4组平行试验，探讨土体离子迁移、电学参数、膨胀性能等物理化学方面的变化.试验结果表明，Al3+迁移能力远大于Cu2+和Fe2+，后两者难以在电场力的作用下移动，电极反应生成的金属离子对电渗排水基本没有促进作用；电渗削弱了蒙脱石的乙二醇膨胀性，且除铜电极外，铝、铁、EKG电极下电渗对靠近阴极的土的膨胀性抑制作用更强；电渗作用降低了蒙脱石的zeta电位绝对值；铝电极下Al3+的渗入严重降低了Ca2+的排出量，铁电极下Fe3+和Fe2+的渗入束缚了阳极附近土体中Na+的迁移；铁电极和EKG电极对土体有酸化作用，而铜电极、铝电极则不然.
Abstract:

Single mineral montmorillonite was taken as electro-osmosis object to explore the microcosmic mechanism of electro-osmosis. Four sets of parallel tests were designed using self-made metal electrodes and EKG (electro-kinetic geosynthetics) electrodes. The results of electro-osmosis were analyzed; the changes of the physicochemical aspects such as ion migration, electrical parameters and swelling properties were discussed. The experimental results show that Al3+ migration ability is much greater than Cu2+ and Fe2+, the latter two are difficult to move under the action of electric field force, the metal ions produced by the electrode reaction have little effect on the electro-osmotic drainage; the electro-osmosis weakened the ethylene glycol expansibility of montmorillonite, and in addition to the copper electrode, electro-osmosis under the aluminum, iron, EKG electrode has stronger inhibition on the expansion of soil near the cathode; the electro-osmotic effect reduced the absolute value of zeta potential of montmorillonite; the infiltration of Al3+ in the aluminum electrode seriously reduced the emission of Ca2+, and the infiltration of Fe3+ and Fe2+ in the iron electrode constrained the migration of Na+ in the soil near the anode. The iron electrode and the EKG electrode have acidification effect on the soil, while the copper and aluminum electrodes are not so.
收稿日期: 2017-03-05 出版日期: 2017-11-22
CLC:  TU443  
基金资助:

国家自然科学基金资助项目（41472039，51109168）.
通讯作者: 庄艳峰,男,副教授.orcid.org/0000-0002-9816-5393.     E-mail: zhuang@mail.tsinghua.edu.cn
作者简介: 郭康仕(1994-),男,硕士生,从事电渗脱水固结研究.orcid.org/0000-0003-0500-8725.E-mail:guokangshi@outlook.com
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引用本文:

郭康仕, 庄艳峰, 段伟. 蒙脱石电渗微观机理试验研究[J]. 浙江大学学报(工学版), 2017, 51(12): 2373-2382.

GUO Kang-shi, ZHUANG Yan-feng, DUAN Wei. Experimental study on micro-mechanism of electro-osmosis using montmorillonite. JOURNAL OF ZHEJIANG UNIVERSITY (ENGINEERING SCIENCE), 2017, 51(12): 2373-2382.

链接本文:

http://www.zjujournals.com/eng/CN/10.3785/j.issn.1008-973X.2017.12.009    或    http://www.zjujournals.com/eng/CN/Y2017/V51/I12/2373

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