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浙江大学学报(工学版)
浙江大学学报(工学版)
材料工程     
基于沸石咪唑酯的反蛋白石光子晶体制备研究
杨璨1, 高丰誉1, 陈鹭剑1,2, 崔元靖2, 钱国栋2
1.厦门大学 电子工程系,福建 厦门 361005； 2. 浙江大学 硅材料国家重点实验室,浙江 杭州 310027）
Fabrication of inverted opal photonic crystal based on zeolite imidazolate frameworks
YANG Can1, GAO Feng yu1, CHEN Lu jian1,2, CUI Yuan jing2, QIAN Guo dong2
1.Department of Electronic Engineering, Xiamen University, Xiamen 361005, China; 2. State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027, China
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摘要：

通过将沸石咪唑酯骨架材料(ZIFs)与反蛋白石光子晶体相结合,制备新型反蛋白石光子晶体.以二氧化硅（SiO2）反蛋白石光子晶体与聚苯乙烯（PS）反蛋白石光子晶体作为载体,通过在表面修饰羧基官能团的方式,使ZIF 8中的锌离子与反蛋白石光子晶体表面的羧基配位连接,成功地在2种反蛋白石光子晶体表面上生长了ZIF 8薄膜,制备了2种复合型反蛋白石光子晶体.结果表明,ZIF 8薄膜保持了ZIF 8原有的晶体特性,在反蛋白石光子晶体上覆盖均匀致密,表现出了较好的结合力.复合型反蛋白石光子晶体的光子带隙与原始的反蛋白石光子晶体相比产生了移动,与预测相符.
Abstract:

New composite inverted opal photonic crystals were fabricated combining zeolite imidazolate frameworks (ZIFs) with inverted opal photonic crystals. Silicon dioxide (SiO2) inverted opal photonic crystals and polystyrene (PS) inverted opal photonic crystals were used as support, and their surface was modified with carboxyl groups. The carboxyl groups prompt the adhesive of ZIF 8 by coordinating to the apical sites of the Zn2 units, and make ZIF 8 films grow on the two kinds of inverted opal photonic crystals successfully. Results showed that ZIF 8 films maintained the crystalline nature of ZIF 8. They were of nice connection with the inverted photonic crystals and the growth of which was uniform and dense. The composite inverted opal photonic crystals had a shift in photonic band gaps comparing to the original inverted photonic crystal, which accorded well with the predict results.
出版日期: 2016-04-01
:  O 648  
基金资助:

中央高校基本科研业务费专项资金资助项目(20720140518)；浙江大学硅材料国家重点实验室开放课题资助项目(SKL2015 02).
通讯作者: 陈鹭剑,男,副教授.ORCID: 0000 0002 4156 019X.     E-mail: lujianchen@xmu.edu.cn
作者简介: 杨璨(1989—),男,硕士生,从事有机无机杂化光功能材料的研究.ORCID: 0000 0003 1607 0540. E-mail: 150146021@qq.com
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杨璨, 高丰誉, 陈鹭剑, 崔元靖, 钱国栋. 基于沸石咪唑酯的反蛋白石光子晶体制备研究[J]. 浙江大学学报(工学版), 10.3785/j.issn.1008-973X.2016.04.027.

YANG Can, GAO Feng yu, CHEN Lu jian, CUI Yuan jing, QIAN Guo dong. Fabrication of inverted opal photonic crystal based on zeolite imidazolate frameworks. JOURNAL OF ZHEJIANG UNIVERSITY (ENGINEERING SCIENCE), 10.3785/j.issn.1008-973X.2016.04.027.

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http://www.zjujournals.com/eng/CN/10.3785/j.issn.1008-973X.2016.04.027    或    http://www.zjujournals.com/eng/CN/Y2016/V50/I4/799

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